9th International Science Congress (ISC-2019).  International E-publication: Publish Projects, Dissertation, Theses, Books, Souvenir, Conference Proceeding with ISBN.  International E-Bulletin: Information/News regarding: Academics and Research

The oxidation of 2,4-dinitrophenylhydrazone to Carbonyl compound Emphasizing on the HMTA-2Br2

Author Affiliations

  • 1Department of Chemistry, Islamic Azad University, North Tehran Branch, IRAN

Res. J. Recent Sci., Volume 4, Issue (3), Pages 80-90, March,2 (2015)

Abstract

HMTA-2Br2 is a yellow solid with uniform shape which makes the oxidation of 2,4- dinitrophenylhydrazone made of Aldehyde and Ketone to carbonyl combination possible. The advantages in using the HMTAB are mentioned as the hydrolysis with minimum period of time, moderate condition for the reaction, the optimal characteristic of the oxidant to the Br2 and most of the common oxidants, the certainty of the end of the reaction, the facilitation of the reaction collection which is possible with the simple extraction process, and the lack of using the complex system and the lack of extra oxidation.

References

  1. Organic Chemistry, Thornton Morrison, R. 6th edition, Prentice Hall; (1992)
  2. Karabatsos G.J., Shapiro B.L., Vane F.M., Fleming J.S. and Ratha J.S., J.Am. Chem. Soc., 85, 2784 (1963)
  3. Cheronis N.D., Entriken J.B., Hodnett E.M., Semimicro Qualitative Organic Analysis, 3rd Ed.; Interscience: New York, (1965)
  4. Robert R.M. and Gilbert J.C., Modern Experimental Organic Chemistry, 3rd Ed.; Saunders College: Philadelphia, (1979)
  5. Karabatsos G.J., Shapiro B.L., Vane F.M., Fleming J.S., Rahtha J.S., J. Am. Chem. Soc., 85, 2784 and refrences therein, (1963)
  6. Van Duin H., Thesis, Free University of Amsterdam, (1961)
  7. Shriner R.L., Fuson R.C., Curtin D.Y., Morill T.C., Hermann K.F., The Systematic Identification of organic Compounds, Wiley; 8 edition (2004)
  8. Kerman Albert, Hamel, Dr Mohammadreza Nori, Dr Seid Mohammad Bloorchian, Basic Organic chemistry, second vol.,http://dr-karimzare.com/(2013)
  9. Fieser L., Reagents for Organic Synthesis, Vol.1, Wiley, (1967)
  10. Alam A., Takaguchi, Y., Ito, H.; Yushida, T.; Tsuboi, S., Tetrahedron 611909. (2005)
  11. Chattaway F.D., Wadmore, J.M., J. Chem. Soc. 81, 191.(1902)