A New Simple Ester Ionophore Based Calcium Ion Selective Electrode ā€“Preparation and its Analytical Application

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A New Simple Ester Ionophore Based Calcium Ion Selective Electrode − Preparation and its Analytical Application

Author Affiliations

¹Department of Chemistry, Avinashilingam Institute for Home Science and Higher Education for Women Coimbatore- 641043, Tamilnadu, INDIA

Res. J. Recent Sci., Volume 3, Issue (ISC-2013), Pages 362-365, (2014)

Abstract

A new simple efficient calcium ion selective electrode has been prepared using simple ester. A heterogeneous precipitate has been used as ion carriers for the preparation of Ca (II) selective membrane sensor. The sensor exhibits a near Nernstian response for Ca(II) ion over a concentration range of 1.0 x 10^-4M to 1.0x10^-1M. The proposed sensors revealed relatively good selectively and high sensitivity for Ca(II)over a mono and divalent cations and anions . It can be used within the pH range of 3.42 to 6.24. The effect of medium and the selectivity coefficient values were evaluated using fixed interference method found to give a better response. It was also successfully used in the analysis of concentration of calcium in various real samples.

References

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Mank M., Reiff D.F., Heim N., Friedrich M.W., Borst A. and Griesbeck O., A FRET- Based Calcium Biosensor with Fast Signal Kinetics and High Fluorescence Change, Biophysical Journal., 90(5), 1790–1796 (2006)
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Ashok Klumar Singh and Sameena Mehtab, Calcium(II)-selective potentiometric sensor based on -furildioxime as neutral carrierSensors and Actuators B., 123(1), 429–436 (2007)
Erol Akyilmaz and Ozge Kozgus., Determination of calcium in milk and water samples by using catalase enzyme electrode, Food Chemistry., 115, 347–351 (2009)
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[ref1] Shamsipur M., Soleymanpour A., Akhond M., Sharghi H. and Massah A. R., Uranyl-selective PVC membrane electrodes based on some recently synthesized benzosubstituted macrocyclic diamides, Talanta., 58(2), 237–246 (2002)

[ref2] Zhang Z.R. and Yu R.Q., The synthesis and membrane transport characteristics of macrocyclic polyether ligands composed of 1,10-phenanthroline as carriers for primary amine species, Talanta., 41(2), 327–333 (1994)

[ref3] Singh A.K., Saxena P., Mehtab S. and Gupta B., Strontium(II)-selective electrode based on a macrocyclic tetraamide, Talanta., 69(2), 521–526 (2006)

[ref4] Singh A.K., Saxena P. and Panwar A., Manganese(II)-selective PVC membrane electrode based on a pentaazamacrocyclic manganese complex, Sensors and Actuators B., 110(2), 377–381 (2005)

[ref5] Ganjali M.R., Razavi T., Dinarvand R., Riahi S. andNorouzi P., New Diltiazem Potentiometric Membrane Sensor Stands on Theoretical Calculations as a Useful Device for Diltiazen Hydrochloride Analysis in Pharmaceutical Formulation and Urine, Int. J. Electrochem. Sci., 3(12) ,1543–1558 (2008)

[ref6] Ganjali M.R., Memari Z., Faridbod F. and Norouzi P., Samarium Biosensor: An Asymetric Potentiometric Membrane Sensor , Int. J. Electrochem. Sci., 3(10), 1169–1179 (2008)

[ref7] Beheshti S.S. and Amini M.K., A simple and selective Flow –Injection potentiometric method for determination of iodide based on a Coated Glassy Carbon ElectrodeSensor, Int. J. Electrochem. Sci.,2(10), 778–787 (2007)

[ref8] Zhang H., Zhang Z., Li J. and Sh. Cai., Effects of Mg2+ on Supported Bilayer Lipid Membrane on a Glassy Carbon Electrode during Membrane Formation, Int. J. Electrochem. Sci., 2(10), 788–796 (2007)

[ref9] Paker P., McGraw-Hill Concise Encyclopaedia of Science and Technology, McGraw-Hill, New York, NY, USA, 1994

[ref10] Souza S.F.D., Microbial biosensors, Biosensors and Bioelectronics., 16(6), 337–353 (2001)

[ref11] White P.J. and Broadley M.R., Calcium in Plants, Ann.Bot., 92(4), 487-511 (2003)

[ref12] Mank M., Reiff D.F., Heim N., Friedrich M.W., Borst A. and Griesbeck O., A FRET- Based Calcium Biosensor with Fast Signal Kinetics and High Fluorescence Change, Biophysical Journal., 90(5), 1790–1796 (2006)

[ref13] Lakshminarayanaiah N., Calcium Ion Selective Electrode, J. Membrane Science., 255-271 (1981)

[ref14] Ashok Klumar Singh and Sameena Mehtab, Calcium(II)-selective potentiometric sensor based on -furildioxime as neutral carrierSensors and Actuators B., 123(1), 429–436 (2007)

[ref15] Erol Akyilmaz and Ozge Kozgus., Determination of calcium in milk and water samples by using catalase enzyme electrode, Food Chemistry., 115, 347–351 (2009)

[ref16] Fujita H. Park J. Meissner R. Duclous O. Van Lintel H. and Kenaced P., 19th International conference on miniaturized systems for chemistry and Life Sciences, 3-7 October 2010, The Netherlands, (2010)

[ref17] Craggs A., Moody G.J. and Thomas J.D.R., PVC matrix membrane ion-selective electrodes. Construction and laboratory experiments,J.Chem.educ., 51 (8), 541 (1974)