International E-publication: Publish Projects, Dissertation, Theses, Books, Souvenir, Conference Proceeding with ISBN.  International E-Bulletin: Information/News regarding: Academics and Research

Red Mud as Adsorbent to Remove Lead (II) from Aqueous Solutions

Author Affiliations

  • 1Department of Chemistry, Kirodimal Institute of Technology Raigarh, CG, INDIA
  • 2 Department of Chemistry, Dr. C.V. Raman University Bilaspur, CG, INDIA
  • 3 Department of Chemistry, K. Govt. Arts and Sc. College Raigarh, CG, INDIA

Res. J. Recent Sci., Volume 3, Issue (7), Pages 18-27, July,2 (2014)

Abstract

Batch experiments under different experimental conditions have been performed to evaluate the adsorption characteristics of red mud. Freundlich and Langmuir adsorption isotherm models have been used to discuss the data obtained. Kinetics of adsorption have been discussed using Lagergren first-order equation, pseudo-second-order equation and intra-particle diffusion models. Thermodynamic parameters such as change in free energy G, change in enthalpy H and change in entropy S have been evaluated and discussed to know the spontaneity and feasibility of the process.

References

  1. Bhatnagar A. and Minocha A.K., Conventional and nonconventional adsorbents for removal of pollutants from water – A review, Indian J.Chem.Tech.,13, 203-217 (2006)
  2. Karthika C. and Sekar M., Removal of Hg(II) ions from aqueous solution by acid acrylic resins : A study through adsorption isotherms analysis, I.Res.J.Environment.Sci., 1(1), 34-41(2012)
  3. Singh Dhanesh and Singh A., Chitosan for the removal of chromium from waste water., I.Res.J.Environment.Sci., 1(3), 55-57(2012)
  4. Samuel P., Ingmar P., Boubia C. and Daniel L., Trivalent chromium removal from aqueous solutions using raw natural mixed clay from BURKINA FASO., I.Res.J.Environment Sci., 2(2), 30-37 (2013)
  5. Kini S.M., Saidutta M.B., Murty V.R.C. and Kadoli S.V., Adsorption of basic dye from aqueous solution using ACl treated saw dust (Lagerstroemia microcorpa): Kinetic , Modeling of Equilibrium, Thermodynamic, I. Res. J. Environment.Sci., 2(8), 6-16 (2013)
  6. Haq B.I.U., Elias N.B. and Khanam Z., Adsorption studies of Cr(VI) and Fe(II) aqua solution using rubber tree leaves, I.Res.J.Environment.Sci., 2(12), 52-56 (2013)
  7. Nadaroglu H. and Kalkan E., Removal of cobalt (II) ions from aqueous solutions by using alternative adsorbent industrial red mud waste material.l, Int.J.Phy.Sciences., , 1386-1394 (2012)
  8. Han S.W., Kim D.K., Hwang I.G. and Bae J.H., Development of Pellet-type Adsorbents for Removal of Heavy Metal Ions from Aqueous Solutions using Red Mud, J.Ind.Eng.Chem., 8(2), 120-125 (2002)
  9. Kim J.S., Han S.W., Hwang I.G., Bae J.H. and Tokunaga S., Astudy on removal of Pb++ ion using pellet-type red mud adsorbents, Env.Eng.Res., 7(1), 33-37(2002)
  10. Mobasherpour I., Salahi E. and Asjodi A., Research on the batch and fixed bed column performance of red mud adsorbents for lead removal, Canadian Chemical Transactions, 2(1), 83-96 (2014)
  11. Das B., Mondal N.K., Roy P. and Chatterji S., Equilibrium, Kinetic and Thermodynamic Study on chromium(VI) removal from aqueous solutions using Pistia Stratiotes Biomass, Chem Sci Trans., 2(1),85-104 (2013)
  12. John C., Interpretation of Infrared Spectra, A Practical Approach,Encyclopedia of Analytical Chemistry, R.A.Heyers(Ed.), John Wiley & Sons Ltd. Chichester, 10815 – 10837 (2000)
  13. Ekrem Kalkan, et.al., Bacteria – Modified Red Mud for Adsorption of Cadmium Ions from Aqueous Solutions, Pol.J.Environ. Stud., 22(2), 417–429 (2013)
  14. Tsai W.T. and Chen H.R., Removal of malachite green from aqueous solution using low-cost chlorella-based biomass, J Hazard Mater., 175(1-3), 844-849 (2010)
  15. Sarin V. and Pant K.K., Removal of chromium from industrial waste by using eucalyptus bark, Bioresource Technol., 97(1), 15-20 (2006)
  16. Wongjunda J. and Saueprasearsit P.,Biosorption of Chromium(VI) using rice husk ash and modified husk ash Environ Res. J., 4(3), 244-250 (2010)
  17. Brummer G.W., Importance of Chemical Speciation in Environmental Process (Springer Verlag, Berlin) (1986)
  18. Bansal M. Singh D, Garg V K, Rose P., Use of agricultural waste for the removal of nickel ions from aqueous solutions: Equilibrium and kinetic studies, World Acad.Sci.Eng.Technol., 51, 431-437(2009)
  19. Anirudhan T.S. and Radhakrishnan P.G., Thermodynamics and kinetics of adsorption of Cu(II) from aqueous solutions onto a new cation exchanger derived from tamarind fruit shell, J.Chem.Thermodynamics., 40(4), 702-709 (2008)
  20. Lagergren S., About the theory of so-called adsorption of soluble substsnces,der Sogenanntenadsorption geloster stoffe Kungliga Svenska psalka de Miens Handlingar., 24, 1-39(1898)
  21. Ho Y.S. and Mckay G., The kinetics of sorption of divalent metal ions onto sphagnum moss peat., Water Res. 34(3),735-742 (2000)
  22. Weber W.J. and Morris J.C., Kinetics of adsorption on carbon from solution, J. Saint. Eng. Div. Am. Soc. Eng., 89, 31-60 (1963)
  23. Kumar P.S., Ramakrishnan K., Kirupha S.D and Sivanesan S. Thermodynamic and Kinetic studies of cadmium adsorption from aqueous solution onto rice husk, Braz.J.Chem.Eng., 27, 347 (2010)
  24. Arivoli S., Hema M., Karuppaiah M. and Saravanan S., Adsorption of chromium ion by acid activated low cost carbon-Kinetic, Mechanistic,Thermodynamic and Equilibrium studies, E-Journal of Chemistry., 5(4), 820-831 (2008)
  25. Senthilkumar P., Ramalingam S., Sathyaselvabala V., Kirupha D.S. and Sivanesan S., Desalination, 266(1-3), 63-71 (2011)
  26. Nevine K.A., Removal of direct blue-106 dye from aqueous solution using new activated carbons developed from pomegranate peel: Adsorption equilibrium and kinetics, J. Haz. Mat.., 165(1-3), 52-62 (2009)
  27. Singh Dhanesh and Rawat N.S., Bituminous coal for the Removal of Cd rich water, Ind. J. Chem. Technol., 1, 266-270 (1994)
  28. Singh Dhanesh and Rawat N.S., Sorption of Pb(II) by bituminous coal, Ind. J. Chem. Technol., 2, 49-50 (1995)