International E-publication: Publish Projects, Dissertation, Theses, Books, Souvenir, Conference Proceeding with ISBN.  International E-Bulletin: Information/News regarding: Academics and Research

Generation of Nanostructured MgO Particles by Solution Phase Method

    , , ,

Author Affiliations

  • 1Department of Chemistry, Government Engineering College, B.M. Road, Ramanagara, INDIA
  • 2 Department of P.G. Studies and Research in Chemistry, Kuvempu University, Shankaraghatta, INDIA
  • 3Department of Chemistry, Srinivas School of Engineering, Mukka, Mangalore, INDIA
  • 4Department of Chemistry, Sri Siddaganga College of Arts, Science and Commerce, Tumkur, INDIA

Res.J.chem.sci., Volume 5, Issue (5), Pages 13-18, May,18 (2015)

Abstract

In this contribution, disc like nanosized MgO particles were successfully synthesized by solution-phase method using magnesium chloride (MgCl) and sodium hydroxide (NaOH) in ethanol medium. The ethanol and water content were varied and the generated precursor compound was calcined for an hour at temperature of 300 °C. Samples were characterized by XRD, SEM, FT-IR and UV-Vis spectroscopic techniques. The crystallite sizes were in the range of 17–35 nm based on Debye-Scherrer equation. Scanning electron photomicrographs suggest that all the samples were well crystalline, randomly oriented disc like morphology. The FT-IR result shows strengthen other results and also blue shift was noticed in UV–Vis absorption spectra.

References

  1. Kenneth J., Klabunde and Peter K. Stoimenov., Dekker encyclopedia of Nanoscience and Nanotehnology, VI Volume, CRC Press, (2004)
  2. Elaheh Esmaeili., Abasali Khadadi and Yadollah mortazavi., Structure and microstructure of combustion synthesised MgO Nanoparticle synthesis using polyethylene glycol and sorbitol, J. of European ceramic society, 29, 1061-1068 (2009)
  3. Yong Cheol Hong and Han Sup Uhm, Synthesis of nanopowder in atmospheric microwave plasma torch, Chem. Phy. Letters, 422, 174-178 (2006)
  4. Cover story, Nanomaterials, A Big Market Potential, Chemical Week, October 16, pi 7, (2002)
  5. Li Y. and Klabunde K.J., Langmuir, 7, 1388, (1991)
  6. Koper O., Klabunde K.J., US. Patent No. 6057488, (2000)
  7. Rizwan wahab., Ansari S.G., Dar M.A., Kim Y.S. and Shin H.S., Synthesis of MgO nanoparticles by sol-gel process, Materi.sci. forum, 558-559, 983-986 (2007)
  8. Cui Z., Meng G.W., Haung W. D., Wang G.Z. and L. D. Zhang, Mater. Res. Bull, 35, 1653 (2000)
  9. Kim H.W., Shim S.H. and Chongmu L., J. of Korean Phys. Soc, 49(2), 628 (2006)
  10. Peter K.S., Rosalyn L., George L.M. and Klabunde J.K., Langmuir, 18, 6679 (2002)
  11. Makhluf S., Rachel D., Yeshayahu N., Yaniv A., Raz J. and Aharon G., Adv. Func. Mater, 15, 1708 (2005)
  12. Poullikkas A., Energy Conversion Manage, 45, 1725 (2004)
  13. Guo X. L., Liu Z. G., Chen X. Y., Zhu S. N., Xiong S. B., Hu W. S. and Lin C. Y., J. Appl. Phys, 29, 1632 (1996).
  14. Li Y.R., Liang Z., Zhang Y., Zhu J., Jiang S.W. and Wei X. H., Thin Solid Films, 489, 245 (2005)
  15. Parkin S.P.P., Kaiser C., Panchula A., Rice P.M., Hughes B., Samant M. and Yang S.H., Nat. Mater, 3, 862-867 (2004)
  16. Yuasa S., Nagahama T., Fukushima A., Suzuki Y. and Ando K., Nat. Mater, 3, 868–871 (2004)
  17. Yan L., Lopez C.M., Shrestha R. P., Irene E. A., Suvorova A. A. and Saunders M., Appl. Phys. Lett, 88, 142901 (2006)
  18. Posadas A., Walker F.J., Ahn C.H., Goodrich T.L., Cai Z. and Ziemer K.S., Appl. Phys. Lett, 92, 233511 (2008)
  19. Fedorov P.P., Tkachenko E.A., Kuznetsov S.V., Voronov V.V. and Lavrishchev S.V., Preparation of MgO Nanoparticles, Neorganicheskie Materialy, 43(5), 574–576 (2007)
  20. Itatani K., Yasuda R., Howell F.S. and Kishioka A., J Mater Sci., 32, 2977 (1997)
  21. Lopez T., Garcia-Cruz I. and Gomez R., Synthesis of Magnesium Oxide by the Sol-Gel Method: Effect of the pH on the Surface Hydroxylation, Journal of catalysis, 127, 75-85 (1991)
  22. Baranova A.N., Kapitanova O.O., Panin G.N. and Kang T.V., ZnO/MgO Nanocomposites Generated from Alcoholic Solutions, Russian Journal of Inorganic Chemistry, 53(9), 1366-1370 (2008)
  23. Dae Jong Seo, Seung Bin Park, Yun Chan Kang and Kwang Leong Choy, Formation of ZnO, MgO and NiO nanoparticles from aqueous droplets in flame reactor, Journal of Nanoparticle Research, 5, 199–210 (2003)
  24. Mikhail Pashchanka, Rudolf C. Hoffmann and Jhorg J., Schneider, Controlled synthesis and characterisation of MgO nanoparticles, thin films and polycrystalline nanorods derived from an Mg (II) single source precursor, Journal of Materials Chemistry, (2009)
  25. Zhanlai Ding, Cunran An, Qiang Li, Zhezhe Hou, JianqiangWang, Haibo Qi and Fangjuan Qi, Preparation of ITO Nanoparticles by Liquid Phase by Coprecipitation Method, Journal of Nanomaterials, (2010)
  26. Singanahally T. Aruna, Alexander S. and Mukasyan, Combustion synthesis and nanomaterials, Current Opinion in Solid State and Materials Science, 12, 44-50 (2008)
  27. Hur J. M., Kim I. S., Lee W. K., Cho S. H., Seo C. S. and Park S.W., J. Ind. Eng. Chem, 10, 442 (2004), Kim K. D., Kim S.S. and Kim H.T., J. Ind. Eng. Chem, 11, 584 (2005)
  28. Xia Y.N., Rogers J.A. and Paul K.E. et al., Unconventional methods for fabricating and patterning nanostructures, Chem Rev, 99, 1823-1848 (1999).
  29. Ahmadi T.S., Wang Z.L. and Green T.C. et al., Shapecontrolled synthesis of colloidal platinum nanoparticles. Science, 272, 1924-1926 (1996)
  30. Nikoobakht B. and El-Sayed M.A., Preparation and growth mechanism of gold nanorods (NRs) using seedmediated growth method, Chem Mater, 15, 1957-1962 (2003)
  31. Joel A. Haber, Nilesh V. Gunda and William E. Buhro, Nanostructure by design: Solution-phase-processing routes to nanocrystalline metals, ceramics, intermetallics and composites, journal of Aerosol sci, 29(5-6), 637-645 (1998)
  32. Longshan Xu, Xiaohua Chen, YurongWu and Chuansheng Chen, Solution-phase synthesis of singlecrystal hollow Cu Ospheres with nanoholes, Nanotechnology, 17, 1501–1505 (2006)
  33. Dongning Yang, JinZhang, Rongming Wang and Zhongfan Liu, Solution phase synthesis of magnesium hydroxide sulfate hydrate nanoribbons, Nanotechnology, 15, 1625–1627 (2004)
  34. Louis A. Carpino, Shahnaz Ghassemi, Dumitru Ionescu and Mohamed Ismail, Dean Sadat-Aalaee, Rapid, Continuous Solution-Phase Peptide Synthesis: Application to Peptides of Pharmaceutical Interest, Organic Process Research and Development, 7, 28−37 (2003)
  35. Bryan D. Wood, Valentin Mocanu and Byron D. Gates, Solution-Phase Synthesis of Crystalline Lithium Niobate Nanostructures, Adv. Mater, 20, 4552–4556 (2008)
  36. Ragone D.V., Themodynamics of materials, Vol II. Jhone Wiley and sons Inc. (1995)
  37. Haxia Niu,Qing Yang, Kaibian Tang and Yi Xie, Large scale synthesis of single crystalline MgO with bone like nanostructures, J. of Nanoparticle research, 8, 881-888 (2006)