Biotreatment of a Triphenylmethane dye Solution using Medicinal Plant Rhizome: Acorus Calamus

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Biotreatment of a Triphenylmethane dye Solution using Medicinal Plant Rhizome: Acorus Calamus

Author Affiliations

¹Department of chemistry, Sri Shakthi Institute of Engineering and Technology, Coimbatore, INDIA
²Department of Chemistry, Kongunadu Arts and Science College, Coimbatore, INDIA
³Department of chemistry, Kalaignar Karunanidhi Institute of Technology, Coimbatore, INDIA
⁴Department of chemistry, National College, Tiruchirappalli, INDIA

Res.J.chem.sci., Volume 5, Issue (4), Pages 13-19, April,18 (2015)

Abstract

This article utilizes still popular medicinal herbal plant Acorus calamus rhizome as a decisive substitute for exclusion of Basic Green 4 (BG 4), a cationic dye from its aqueous solutions by making use of batch investigational system. Further plausible mechanisms were achieved by correlating experimental values with the predicted kinetic models thus exploiting high significant rate statistics of the model preferred. Experimental biosorption data were modelled by Langmuir, Freundlich, Tempkin, Dubinin-Radushkevich (D-R) isotherm, Redlich-Peterson (R-P) isotherm, Harkins- Jura (H-J) isotherm and Generalised isotherms. The biosorption route followed the Langmuir isotherm model with high coefficients of correlation (R > 0.99).Thermodynamic parameters suggest that the biosorption process is spontaneous and endothermic in nature. Overall, this article summarizes the efficacy of herbal biosorbent for the elimination of BG 4

References

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[ref1] Anna Witek-Krowiak, Analysis of influence of process conditions on kinetics of malachite green biosorption onto beech sawdust, Chem. Eng. J., 171976-985 (2011)

[ref2] Bulut E. and Ozacar Sengil. I.A., Adsorption of malachite green onto bentonite: Equilibrium and kinetic studies and process design, Microporous and Meso-porous Materials, 115, 234–246 (2008)

[ref3] Mahmoodi N.M., Hayati B., Arami M. and Mazaheri F., Single and binary system dye removal from colored textile wastewater by a dendrimer as a polymeric nanoarchitecture: Equilibrium and kinetics, J. Chem. Eng. Data, 55, 4660–4668 (2010)

[ref4] Culp S.J., Mellick P.W., Trotter R.W., Greenlees K.J., Kodell R.L. and Beland F.A., Carcinogenicity of malachite green chloride and leucomalachite green in 566 B6C3F1 mice and F344 rats, Food Chem. Toxicol., 44,1204–1212 (2006)

[ref5] Lagergren S. and Sven K., Zurtheorieder sogenannten adsorption gelöster stoffe, Vetenskapsakad Handl, 24, 1–39 (1898)

[ref6] Ho Y.S., Second-order kinetic model for the sorption of cadmium onto tree fern : A comparison of linear and non-linear methods, Water Res. 40, 119–125 (2006)

[ref7] Weber W.J. and Morris J.C., Kinetics of adsorption on carbon from solution, J. Sanitary Eng. Div. Proc. Am. Soc. Civil Eng.,89, 31–59 (1963)

[ref8] Neha Gupta, Atul Kumar Kushwaha and Chattopadhyaya M.C., Adsorption studies of cationic dyes onto Ashoka (Saraca asoca) leaf powder, Journal of the Taiwan Institute of Chemical Engineers, 43, 604–613 (2012)

[ref9] Aylin Altnsk, Emel Gur and Yoldas Seki, A natural sorbent, Luffa cylindrica for the removal of a model basic dye, Journal of Hazardous Materials, 179, 658–664 (2010)

[ref10] Garima Mahajan and Dhiraj Sud, Modified agricultural waste biomass with enhanced responsive properties for metal-ion remediation: A green approach, Appl Water Sci, 2, 299–308 (2012)

[ref11] Chowdhury S and Das P, Mechanistic kinetic and thermodynamic evaluation of adsorption of hazardous malachite green onto conch shell powder, Sep Sci Technol,46, 1966–1976 (2011)

[ref12] Sagnik Chakraborty, Shamik Chowdhury, Papita Das Saha, Insight into biosorption equilibrium, kinetics and thermodynamics of crystal violet onto Ananas comosus (pineapple) leaf powder, Appl Water Sci, 135–141 (2012)

[ref13] Temkin M.J. and Pyzhev V., Acta Physiol. Chem. U.S.S.R. 12, 217–222 (1940)

[ref14] Dubinin MM and Radushkevich LV., Equation of the characteristic curve of activated charcoal, Chem Zentr,, 875 (1947)

[ref15] Sonawane G.H. and Shrivastava V.S., Kinetics of decolourisation of malachite green from aqueous medium by maize cob (Zea maize): An agricultural waste, Desalination, 247, 430-441 (2009)

[ref16] Redlich O and Peterson DL., A useful adsorption isotherm, J Phys Chem, 63, 1024-6 (1959)

[ref17] Tahir S.S. and Rauf N., Removal of cationic dye from aqueous solution onto bentonite, Chemosphere,63,1842–1848 (2006)

[ref18] Mittal A., Krishnan L., Gupta V.K., Removal and recovery of malachite green from wastewater using an agricultural waste material, de-oiled soya, Sep. Purif. Technol., 43 125–133 (2005)

[ref19] Mittal A., Adsorption kinetics of removal of a toxic dye, malachite green from waste water using hen feathers, J. Hazard. Mater, B133,196–202 (2006)