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Study on X-Ray Diffraction of some Mn (II), Fe (III), Co(II), Ni(II), Cu(II), Zn(II), Complexes on the basis of Mixed ligands

Author Affiliations

  • 1Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad, 431004, MH, INDIA

Res.J.chem.sci., Volume 5, Issue (10), Pages 1-6, October,18 (2015)

Abstract

Comparative studies on the x-ray diffraction parameter of some transition metal complexes such as Mn(II), Fe(III), Co(II), Ni(II), Cu(II) and Zn(II), has been synthesized by 4-methoxyplenylmaine and salicylaldehyde, o-vanillin having equiamolar ratio of 1:1:1(metal : L1 : L2) in the same solvent. These complexes were different physico-chemical properties such as different color, different melting points and different crystal systems. All the complexes of XRD studies indicate that monoclinic crystal structure has been proposed for the mixed ligands metal complexes. The XRD data were also being used for the determination of various parameter, unit cell volume and miller indices values (h, k, l). The XRD measurement is to be determine the dimensions and shape of unit cell and to identify the detailed structure of the molecule such as tetrahedral, octahedral or square planer geometry.

References

  1. Bish D.L. and Post J.E., Editors, Diffraction, Reviews in Mineralogy, Mineralogical Society of America(1990)
  2. Wall B., Driscoll C., Strong J. andSuitability of Different Preparations of Thermo luminescent Lithium Borate for Medical DosimetryPhysical Medical biology, 1023-1034(1982)
  3. Azaroff and Burger, the Powder Method, McGraw Hill London (1958)
  4. Klop E.A .and Lammers M., Polymers,39, 5987 (1998)
  5. Sleema B. and Parameshwaran G., 961 (2002)
  6. Azaroff and Burger, The Powder Method, McGraw Hill London (1958)
  7. Dutt N.K. and Rahut S., J. Inorg. Nucl. (1970)
  8. Saxena N., Juneja H.D. and Munshi K.N., Chem. Soc., 70, 943 (1993)
  9. Carvajal J.R., Roisnel T. and Winplotr A., Graphic Tool for Powder Diffraction, Laboratories Leon brillouin (ceal 91191 gif suryvette cedex, France, (2004)
  10. Bhattacharya K.C., An Elementary Physics for Indian School, the Indian Press Ltd Allahabad, 105 (1934)
  11. Suryawanshi D.D., Gaikwad S.T., Suryawanshi A.D. and International Journal of recent Technology -3878, 2(3),(2013)
  12. Suryawanshi D.D., Gaikwad S.T. and Rajbhoj A.S., Chemical Science Tranction,3(1), 117-122 (2014)