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A study of Accuracy of Multicomponent analysis of Phenol and cyanide in their binary Solution by Colorimetric Method

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Author Affiliations

  • 1Department of Chemical Engineering, IIT Roorkee, Roorkee, Uttrakhand, INDIA

Res.J.chem.sci., Volume 4, Issue (7), Pages 30-35, July,18 (2014)

Abstract

The present work delineates the accuracy of colorimetric method for the determination of phenol and cyanide in their binary solution. The effect of phenol on cyanide estimation and vice versa has been studied by estimating a known concentration of each pollutant in solutions with different concentration ratios of both phenol and cyanide. Aliquots prepared with constant concentration of one component and varying concentration of the other component were analyzed for the impact studies of both the components on each other. Error calculations were also carried out for estimation of both components in their individual solutions as well as in their binary solutions. Studies of bond formations between components and components with their coloring agents were carried out. The study of effect of coloring agents on the absorbance and corresponding wavelengths were also carried out.

References

  1. Duda A.M., Addressing nonpoint sources of water pollution must become an international priority, Wat. Sci. Tech., 28, 1-11 (1993)
  2. Ma J., Ding Z., Wei G., Zhao H., Huang T., Sources of water pollution and evolution of water quality in the Wuwei basin of Shiyang river, Northwest China, J. Environ. Manage., 90, 1168-1177 (2009)
  3. Agarwal B., Balomajumder C., Thakur P.K., Simultaneous co-adsorptive removal of phenol and cyanide from binary solution using granular activated carbon, Chem. Eng. J.,228, 655-664 (2013)
  4. Montedoro G., Servili M., Baldioli M., Miniati E., Simple and Hydrolyzable Phenolic Compounds in Virgin Olive Oil, 1, Their Extraction, Separation, and Quantitative and Semiquantitative Evaluation by HPLC, J. Agric. Food Chem., 40 1571-1576 (1992)
  5. Ye X., Kuklenyik Z., Needham L.L., Calafat A.M., Automated On-Line Column-Switching HPLC-MS/MS Method with Peak Focusing for the Determination of Nine Environmental Phenols in Urine, Anal. Chem., 77, 5407-5413 (2005)
  6. Kuch H. and Chmiter K.B., Determination of Endocrine-Disrupting Phenolic Compounds and Estrogens in Surface and Drinking Water by HRGC-(NCI)-MS in the Picogram per Liter Range, Environ. Sci. Technol., 35, 3201-3206 (2001)
  7. Folin O. and Denis W., A Colorimetric Method for the determination of Phenols (and Phenol Derivatives) in Urine, J. Biol. Chem.,22, 305-308 (1915)
  8. Tiitto R.J., Phenolic Constituents in the Leaves of Northern Willows: Methods for the analysis of certain Phenolics, J. Agric. Food Chem., 33, 213-217 (1985)
  9. Tracqui A., Raul J.S., Geraut A., Berthelon L., Ludes B., Determination of Blood Cyanide by HPLC-MS, J. Aal. Toxicol., 26, 144-148 (2002)
  10. Chinaka S., Tanaka S., Takayama N., Tsuji N., Takou S., Ueda K., High-Sensitivity Analysis of Cyanide by Capillary Electrophoresis with Fluorescence Detection, Anal. Sci., 17, 649-652 (2001)
  11. Haque M.R. and Bradbury J.H., Total cyanide determination of plants and foods using the picrate and acid hydrolysis methods, Food Chem., 77, 107-114 (2002)
  12. Rockfln R.D. and Johnson E.L., Determination of Cyanide, Sulfide, Iodide, and Bromide by Ion Chromatography with Electrochemical Detection, Anal. Chem., 55, 4-7 (1983)
  13. Cacace D., Ashbaugh H., Kouri N., Bledsoe S., Lancaster S., Chalk S., Spectrophotometric determination of aqueous cyanide using a revised phenolphthalin method, Anal. Chim. Acta., 589, 137-141 (2007)
  14. Fisher F.B., Brows J.S., Colorimetric Determination of Cyanide in Stack Gas and Waste Water, Anal. Chem., 24, 1440-1444 (1952)
  15. Kiran V.R. and Chandrajit B., Simultaneous Adsorptive Removal of Cyanide and Phenol from Industrial Wastewater: Optimization of Process Parameters, Res.J.Chem.Sci., 1, 30-39 (2011)
  16. Schmidt P.C., Glombitza B.W., Quantitative multicomponent analysis of aspirin and salicylic acid in tablets without separation of excipients by means of principal component regression and a classical least squares algorithm. Trends Anal. Chem.,14, 45-49 (1995)
  17. Pavia D.L., Lampman G.M., Kriz G.S, Vyvyan J.R., Spectroscopy, Brooks/Cole, (2007)