Effect of the Micellar Catalysed Hydrolysis of BIS -4-Chloro-3-Methyl Phenyl Phosphate Ester
Author Affiliations
- 1Department of Chemistry, Janta College, Bakewar, Etawah, INDIA
- 2Department of Chemistry, Agra College, Agra, UP, INDIA
Res.J.chem.sci., Volume 3, Issue (8), Pages 63-67, August,18 (2013)
Abstract
The micellar catalysed reactions between hydroxide anions and bis-4-chloro-3-methyl phenyl phosphate ester (bis-4-CMPP) has been examined in buffered medium at pH 8 to10. The first order rate constant (KΨ) for the reaction of OH with 4-CMPP go through maxima with increasing the concentration of cetyltrimethyl ammonium bromide(CTABr). Concentration of the surfactant can be analyzed in terms of Br- ions in micellar pseudophases, which occur readily by aqueous CTABr and calculated second order rate constants.
References
- Fendler J.H. and Fendler E.J., Catalysis in micellar and macro molecular systems, Academic Press, New York (1975)
- Singh A.P. and Yadav G.C., Proc. Nat. Conf. Current Concept. Scie, Educational Research-T.D.C., JAUNPUR, 41-45 (2011)
- Singh A.P., Verma R.C. and Kushwah R.S., J. of ultra chemistry, 9(1), 23-30 (2012)
- Mortinek K., Yatsiimirski A.V. and Berezin I.V., Micellization Solubilization and micro emulsion, Mittal, K.L., Ed. Plenum Press, New York, 2, 489 (1977)
- Romsted L.S. and Mittal K.L., Ed. Plnum Press New York, 2, 50 (1977)
- Quina F.H. and Chaimovich H., J.of Physical Chem., 83, 1844, (1979)
- Chaimovich H., Bonihla J.B.S., Politi M.J., Quina F.H., J.of Physical Chem., 83, 1851 (1979)
- Funasaki N. and Murata A., Chem Pharm Bull.,28, 805 (1980)
- Bunton C.A., Romosted L.S., Supelveda L., J. of Physicai Chem.,84, 2611 (1980)
- Al. Lohedon, H., Bunton, C.A., Romosted, L.S., J. of Physicai Chem., 85, 2123 (1981)
- Bunton C.A., Romosted L.S., Savelli, G., J.of American Chem. Soc.,101, 1253 (1979)
- Bunton C.A., Romosted L.S., Thamabit, J.of American Chem. Soc., 102, 3900 (1980)
- Bunton C.A., Romosted L.S., Savelli, G.,Gan, L.H., Moffat, J.R., J. of Physical Chem.,85, 4118 (1981)
- Al. Lohedon H., Bunton, C.A., J. of Org.Chem.,47, 1160 (1982)
- Bunton C.A., Romosted L.S., Solution behavior of surfactants, Theoretical and Applied Aspects, Mittal, K.L., Ed. Plenum Press, New York, 2, 975 (1982)
- Bunton C.A., Robinson L., J. of Org. Chem.,34, 733 (1969)
- Bunton C.A., Cerichelli G., Ihara Y., Supelveda L., J. of American Chem. Soc,101, 2429 (1979)
- Menger F.M. and Protony C.E., J. of Amer. Chem. Soc.,89, 4968 (1967)
- Bunton C.A. and Junggern S.L., J of Chem. Soc., Perkin Trans.2, 20. 355 (1984)