9th International Science Congress (ISC-2019).  International E-publication: Publish Projects, Dissertation, Theses, Books, Souvenir, Conference Proceeding with ISBN.  International E-Bulletin: Information/News regarding: Academics and Research

Synthesis and Characterization of Co+2, Ni+2, Cu+2, Zn+2 and Hg+2 Complexes with 1,1,2,2-tetrakis (Sodium Thioproponate)ethylene

Author Affiliations

  • 1Teacher Oreparation Institute, Ministry of education, Nineveh, IRAQ

Res.J.chem.sci., Volume 3, Issue (7), Pages 9-14, July,18 (2013)

Abstract

The new ligand 1,1,2,2-tetrakis(sodium thioproponate) ethylene, has been prepared from the reaction of disodium salt of 3-mercaptoproponic acid and tetrachloroethylene in (4:1) molar ratio. Diand tetranuclear complexes were obtained by direct reaction of the above ligand with Co+2, Ni+2, Cu+2, Zn+2 and Hg+2 metal ion in (1:2) and (1:4) ligand to metal molar ratio. The prepared complexes were characterization by elemental analysis, spectral studies (FTIR.,UV/vis), magnetic measurements, conductivity measurements. Electronic spectra and magnetic moment values indicate the presence of tetrahedral geometric around the metal ions.

References

  1. Liang L.C., Metal complexes of chleating diarylamido phosphine ligands, Coord. Chem. Rev., 250, 1152-1177 (2006)
  2. Lin S. J., Ho Y.C., Gau, Synthesis, characterization and structure of group 4 metallocene complexes of some difunctional ligands containing oxygen and sulfur donors, J.Chin.Chem.Soc., 46, 539-544 (1999)
  3. Seleem H.S., Mostafa M., Stefan S.L. and Abdel-Aziz E., Structural Diversity of 3d Complexes of an Isatinic Quinolyl Hydrazone, Res.J.Chem.Sci., 1(5), 67-72 (2011)
  4. Sinfelt J.H., Bimetallic Catalysis, Wiely,New York, (1983)
  5. Yousif E., Farina Y., Grasia A., Salih N. and Salimon J., Structure and Fangicidal activity of some diorganotin (IV) with 2-thioacetic acid -5-phenyl-1,3,4-oxodiazole and benzamidophenyl alanine, Iran, J.Chem.Chem.Eng., 30, 67-72 (2011)
  6. Yousif E., Farina Y., Kasar K., Grasia A. and Ayid K., Complexes of 2-thioacetic acid benzothiazole with some metal ions, Am.J.Appl.Sci., 6(4), 582-585 (2009)
  7. Yousif E., Muaiad F. and Adil H., Synthesis and characterization 2-yl-sulfanyl)-acetic acid ligand, J.AL-NahrainUniv., 14(1), 44-49 (2011)
  8. Banger K.K., Duraj S.A., Fanwick P.E., Hehcmann D.G., Hepp A.F. and Mrtocle R.A., Synthsis and structural characterization of novel indium mercapto derivative [ClIn(SCH2(COO)2]2-[4-MePyH)2]2+, NASAITM,212289 (2004)
  9. Yousif E., Aliwi S.M., Ameer A.A. and Ukal J.R., Improved photostability of PVC films in the presence of 2-thioacetic acid -5-phenyl-1,3,4-oxodiazole complexes, Turk J.Chem., 33, 399-410 (2009)
  10. Buttrus N.H., AL-Smaan S.H. and AL-Asalli S.M., Mono, di-and tri-nuclear complexes of Co(II), Ni(II), Cu(II) and Zn(II) with 1,4-bis(sodium thioglycolate) butane, International J. Chem., 20(1), 37-42 (2010)
  11. Gearvy W.J., The use conductivity measurements in organic solvents for characterization of coordination compounds, Coord.Chem.Rev., , 8-81 (1971)
  12. Deacon G.B. and Philips R.J. (1980), Thermal characteristic of Cu(II) carboxylates with fatty acid, Coord.Chem.Rev., 23, 227-238 (1980)
  13. Mostafa M., Metal Chelates of Hydrazone Ligand Chelating Tendencies of 2-carboxphenylhydrazoacetoacetanilide (2-Cphaaa) Ligand, Res.J.Chem.Sci., 1(7), 1-14 (2011)
  14. Mrinalini L. and Singh A.K.M., Mixed ligand coblt (III) complexes with 1-amidino-o-methylurea and amino acids,Res. J. Chem. Sci., 2(1), 45-49 (2012)
  15. Chaudhary R. and Shelly, Synthesis, spectral and pharmacological study of Cu(II),Ni(II) and Co(II) coordination complexes, Res. J. Chem. Sci., 1(15), 1- (2011)
  16. Bhatti M., Ali S., Huma F. and Shahazadi S., Organo tin (IV) derivatives of N-maleonyl amino acids, Their synthesis and structural elucidation, Turk J.Chem., 29, 463-470 (2005)
  17. AL-Allaf T.A.K. and Buttrus N.H. Coordination complexes of Uranium (VI),Thorium(IV),Cerium (III) and Lanthanum (III) with various multidentade ligands, ABATH AL-YAEMOK,,101-110, (1994)
  18. Nakamoto K., Infrared of inorganic and coordination compounds, 6th Edition, John Wiley New York (1997)
  19. Saleem H.S., Ramadadan A.A.T., Taha A. and Samy F.,Unreported coordination behavior of a squaric bis(hydrazine) ligand, Res. J.Chem. Sci., 1(4), 109-116 (2011)
  20. AL-Allaf T.A.K., Buttrus N.H. and Hitchcock P.B., Palladium and Platinum (II) complexes with arylthioethene, Asia.J. Chem.,9(2), 187-194 (1997)
  21. Hussein S.S., Mostafa M., Stefan S.L. and ABDEL-Aziz E., Structural diversity of 3d complexes of an isatinic quinolyl hydrazine, Res. J. Chem. Sci., 1(5), 67-72 (2011)
  22. Cotton F.A., Wilkinson G., Murillo C.A. and Bochmann M., AdvanceInorganic Chemistry, 6th Ed., Joh. Wiley and Sons, New York, 810-842 (1990)
  23. Buttrus N.H. and Saeed F.T.,Bis (N-methyl benzimidazolium-2-thio) ethane,propane or butane and its Co(II),Ni(II),Cu(II) and Zn(II) ionic salts, International J.Chem., 22(2),117-122 (2012)
  24. Mohamed A.A., Buttrus N.H. and Younis M.K., New complexes of polyurea with Cu(II), Mn(II) and Cr(II) (Synthesis and characterization, National J.Chem., 38, 333-348 (2010)