@Editorial
<#LINE#>Opportunities and Challenges in Electrochemiclas<#LINE#>Vasudevan@S<#LINE#>Res.J.chem.sci.<#LINE#>
@Research Paper
<#LINE#>Synthesis and Evaluation of Novel Fluorescent Dyes using Microwave Irradiation<#LINE#>Ahmed@K.A.,M.M.@El-Molla,M.S.A.@Abdel-Mottaleb,Mohamed@S.Attia,S.@El-Saadany<#LINE#>3-18<#LINE#>1.ISCA-RJCS-2012-213.pdf<#LINE#> Textile Research Division, National Research Centre, Dokki, Cairo, EGYPT @ Chemistry Department, Faculty of Science, Ein shames University, Cairo, EGYPT @ Questioned Document Examiner, Dept. of Forgery and Counterfeiting Research, Forensic Medicine, Ministry of Justice, Cairo, EGYPT <#LINE#>29/9/2012<#LINE#>5/10/2012<#LINE#> Some new fluorescent dyes were prepared using microwave irradiation. Acetyl coumarine were synthesized via reaction of ethyl acetate with salcilaldhyde. The resultant coumarine under go further reaction with different aldhydes to produce a new series of cuomarines derivatives which based on chalcone moiety. The structures of the synthesized dyes have been investigated using element analysis, IR –spectra, H- NMR, and mass spectra. The using of the synthesized fluorescent dyes in textile printing of polyester and polyamide fabrics was investigated. <#LINE#> @ @ Kinza Aslam, M. Kaleem Khosa, Nazish Jahan and Sofia Nosheen, Synthesis and aplications of coumarin‘pak, J. Pharm. Sci.,23(4), 449-454 (2010) @No $ @ @ Indu Singh, Hemlata Kaur, Sunil Kumar, Arun Kumar, Suman Lata and Ashok Kumar, Synthesis of New Coumarin Derivatives as Antibacterial Agents, International Journal of ChemTech Research,2(3), 1745-1752 (2010) @No $ @ @ Selvam P., Ramlakshmi N., Uma G., Arun Kumar S. and Umamaheswar A., “Synthesis, Characterisation and Biological Evaluation of Novel Coumarin Derivatives,  Rasyan J Chem.,3(2) 275-280 (2010) @No $ @ @ Bardajee G.R., Li A.Y., Haley J.C. and Winnik M.A., The synthesis and spectroscopic properties fluorescent naphthalimide of novel, functional dyes, Dyes and Pigments, 79(1), 24-32 (2008) @No $ @ @ Hunger K., Industrial Dyes: Chemistry, Properties, Applications: Wiley-VCH Verlag GmbH & Co. KGaA (2004) @No $ @ @ Szuster L., Kazmierska M. and Krol I., Fluorescent dyes destined for dyeing high-visibility polyester textile products, Fibres & Textiles in Eastern Europe, 12(1), 70-75 (2004) @No $ @ @ Christie R.M., Fluorescent dyes, Review of Progress in Coloration and Related Topics, 23, 1-18 (1993) @No $ @ @ Sokolowska J., Czajkowski W. and Podsiadly R., The photostability of some fluorescent disperse dyes derivatives of coumarin, Dyes and Pigments, 49(3), 187-91 (2001) @No $ @ @ Jaung J.Y., Matsuoka M. and Fukunishi K., Dicyanopyrazine studies, Part V: Syntheses and characteristics of chalcone analogues of dicyanopyrazine, Dyes Pigments, 40, 11e20 (1998) @No $ @ @ Joko K. and Koga J., Proc. 9th internat, Wool Text conference, 19-26 (1990) @No $ @ @ AATCC AATCC Standard Instrument (2002) @No $ @ @ AATCC, Research Triangle Park, NC (2012) @No $ @ @ DINEN ISO 150 105E04, 6 (1996) @No $ @ @ DINEN ISO 150 105E04, 6 (1997) @No $ @ @ Murata C., Masuda T., Kamochi Y., Todoroki K., Yoshida H. and Nohta H., Improvement of fluorescence characteristics of coumarins: Syntheses and fluorescence properties of 6-methoxycoumarin and benzocoumarin derivatives as novel fluorophores emitting in the longer wavelength region and their application to analytical reagents, Chem Pharm Bull, 53, 750e8 (2005) @No 
<#LINE#>Studies on Atomic Spectroscopic Terms and Term Symbols of Non-equivalent Electrons of d2s1p1 Configuration Using Russell- Saunders Coupling Scheme<#LINE#>Meena@ParmeshwarLal,Nitin@Kumar,@MeenaAnoopSingh,MeenaKamod@Singh<#LINE#>19-24<#LINE#>2.ISCA-RJCS-2013-009.pdf<#LINE#> Department of Chemistry, M.L.S. University, Udaipur, Rajasthan-313001, INDIA @ Department of Chemistry, M.L.V. Govt. College, Bhilwara, Rajasthan-311001, INDIA <#LINE#>11/1/2013<#LINE#>11/2/2013<#LINE#>  Russell-Saunders (R-S) coupling scheme is an important coupling scheme to determine the terms and to assign the term symbols to the terms to the valence electrons of free atoms. The atomic term symbols provide the information about the energy of atomic valence electrons, total spin, total orbital angular momentum, total angular momentum, spectral and magnetic properties of atom. In this proposed work computation is done to determine  all the  possible terms for the non-equivalent valence electrons of d2s1p1 configuration manually and the term symbols are assigned to the terms using Russell-Saunders coupling scheme. The possible microstates calculated for the non-equivalent electrons of d2s1p1 configuration are  540 and the total numbers of atomic spectroscopic terms determined from these microstates are 38 (17 types),  6 are quintets (5 types), 17 are triplets (6 types) and 13 are singlet’s (6 types). The ground state term for the non-equivalent electrons of d2s1p1 configuration is quintet G (5G) and the ground state is quintet G two (5G2).  <#LINE#> @ @  Hollas  J.M., Modern Spectroscopy, Wiley India Pvt. Ltd.,  (2010) @No $ @ @  Mehlman G., Balloffet and Estewa J.M., Far-Ultraviolet Absorption Spectra with Auto-Ionized Levels of Beryllium and Magnesium, Astrophisic J., 157,957-956, (1969) @No $ @ @  Wopg E.Y., Configuration Interaction of the Pr3+ Ion, J. Chem. Phys., 38(4), 976 (1963) @No $ @ @  Lever A.B.P., The Electronic Spectra of Transition Metal Complexes with F (Free Ion) Ground Terms Derivation of Dq and B., J. Chem. Ed., 45, 711-712 (1968) @No $ @ @  Puri B.R., Sharma L.R. and Pathania M.S., Principle of Physical Chemistry, Vishal Publishing  Company, New Delhi (2008) @No $ @ @  Goyal R., M. Phil. Dissertation, MDS University, Ajmer (2007) @No $ @ @  Lee  J.D., Concise Inorganic Chemistry, Chapman and Hall, London (1996) @No $ @ @ Huheey J.E., Keiter E.A. and Keiter R.L., Inorganic Chemistry: Principles of Structure and Reactivity, Harper Collins College, New York (2001) @No $ @ @  Dougles B.E. and McDaniel D.H., Concepts of Model of Inorganic Chemistry, Oxford and IBH Publishing Company, New Delhi (1970) @No $ @ @  Bethe H., Splitting of Terms in Crystals, Amm. Physik, 3, 121 (1929) @No $ @ @  Kiremire E.M.R., A Numerical Algorithm Technique for Deriving Russell-Saunders (R-S) Terms, J.Chem. Education, 64(11), 951-953 (1987) @No $ @ @  Shriver D.F. and Atkins  P.W., Inorganic Chemistry, Oxford University Press, New York  (2002) @No $ @ @  Condon E.U. and Shorttley  G.H.,The theory of atomic spectra, Cambidge University press, London (1963) @No $ @ @  McDaniel D.H., Spin factoring as an aid in the determination of spectroscopic terms, J. Chem. Educ., 54(3), 147 (1977) @No $ @ @  Meena P.L., Jain P.K., Kumar N.,  Meena K.S., and Goyal  R., Study on the atomic term symbols for f4 (M+3 free ion) configuration, J. Chem. Bio. Phy. Sci, 1(2), 188-203 (2011) @No $ @ @  Meena P.L., Jain P.K., Kumar N.and Meena K.S., A comparative study of the atomic term symbols of f3 and f11 configuration, Acta Chim. Pharm. Indica, 2(1), 32-45 (2012) @No $ @ @  Meena P.L., Jain P.K., Kumar N.and Meena K.S., Study on the atomic term symbols for f3 (M3+ free ion) configuration, Int. J. Chem. Sci., 9(3), 1364-1372 (2011) @No $ @ @  Meena P.L., Jain P.K., Kumar N.and Meena K.S., Calculation of atomic spectroscopic terms for non-equivalent electrons of f2 d1 configuration and assigning the term symbols, Asian Journal of Chemistry, 24(12), 5677-5679 (2012) @No 
<#LINE#>Chemical Composition of Kabuli Chickpea Collections under Water Stress and Non-stress<#LINE#>Chandana@Jain,Pratima@Jain<#LINE#>25-28<#LINE#>3.ISCA-RJCS-2013-011.pdf<#LINE#> Department of Life Science, Boston College for Professional Studies, Gwalior, MP, INDIA @ Department of Chemistry, Govt. KRG College, Gwalior, MP,INDIA<#LINE#>16/1/2013<#LINE#>23/2/2013<#LINE#> Estimations of the metabolic products and accumulated ions were made to work out the chemical composition of grain protein, starch, soluble sugars and mineral contents in fourteen Kabuli chickpea samples under water stress to non-stress conditions. Results indicated that a higher amount of grain protein and soluble sugars were found under moisture stress however starch content decreased. Chemical analysis for mineral composition of Kabuli chickpea showed that accumulation of K and Mg increases and total P, Zn, Ca and Fe decreases in the samples of moisture stress environment.  <#LINE#> @ @ Mostafa M., Rady and Maybelle S., Gaballah, Improving Barley Yield Grown Under Water Stress Conditions, Res.J.Recent Sci.,1(6), 1-6 (2012) @No $ @ @ Nayyar Harsh, Satwinder Kaur, Smita Singh and Hari D. Upadhyaya, Differential sensitivity of Desi (small seeded) and Kabuli (large-seeded) chickpea genotypes to water stress during seed filling: effects on accumulation of seed reserves and yield, Journal of the Science of Food and Agriculture 86(13),  2076–2082 (2006) @No $ @ @ Houssen M. Bohabuddien, Quifa Ma., Niel C.Turner and Jairo A Palta, Reaction of chickpea to water stress; yield and seed composition, J. of Science of Food & Agriculture, 81(13), 1288-1291 (2001) @No $ @ @ Lowry O.H., Rosebrough N.J., Farr A.L. and Randall R.J., Protein measurement with the Folin phenol reagent, J. Biol. Chem.193(1), 265–75 (1951) @No $ @ @ Singh Sandeep, Anil K. Gupta and Narinder Kaur, Influence of Drought and Sowing Time on Protein Composition, Antinutrients, and Mineral Contents of  Wheat The Scientific World Journal, 9,  (2012) @No $ @ @ Raut Jyoti, Rupali Ghodeswar, Chavan U.D. and Chavan J.K., Biochemical constituents related to drought tolerance in chickpea, Indian Journal of Agricultural Biochemistry,16(2), 103-104 (2003) @No $ @ @ Nayer Mohammadkhani and Reza Heidari, Drought-induced Accumulation of Soluble Sugars and Proline in Two Maize Varieties, World Applied Sciences Journal,3(3), 448-453 (2008) @No $ @ @ Gunes A., Cicek N.,   Inal A.,   Alpaslan M., Eraslan F.,   E.  Guneri T., Guzelordu Genotypic response of chickpea Cicer     arietinum L.) cultivars to drought stress implemented at pre-and post-anthesisstages and its relations with nutrient uptake and efficiency, Plant Soil Enviorn., 52(8), 368–376 (2006) @No $ @ @ Ning Wangand James K. Daun, Effects of variety and crude protein content on nutrients and anti-nutrients in lentils (Lens culinary) Food Chemistry,  95(3), 493-502 (2006) @No $ @ @ Rahman Abdel A., Shalaby F. and El Monayeri M.O., Effect of moisture  stress on metabolic products and ions accumulation, Plant AndSoil., 34(1), 65-90 (1971) @No $ @ @ Samarah N., Mullen R. and Cianzio S., Size distribution and mineral nutrients of soybean seeds in response to drought stress, J. Plant Nutr27, 815–835 (2004) @No $ @ @ Fageria N.K., Baligar V.C. and Clark R.B., Micronutrients in crop production,  Adv. Agron., 77, 185–67 (2002) @No 
<#LINE#>Kinetics and Mechanism of (salen)MnIII Catalyzed Oxidation of Aryl phenyl Sulfides with Sodium Metaperiodate<#LINE#>Ramasamy@Subramanian,Arunachalam@Chellamani<#LINE#>29-35<#LINE#>4.ISCA-RJCS-2013-013.pdf<#LINE#>Department of Chemistry, Manonmaniam Sundaranar University, Tirunelveli – 627012,INDIA<#LINE#>21/1/2013<#LINE#>2/2/2013<#LINE#> The oxidation of 4-substituted phenyl phenyl sulfides was carried out with several oxo(salen)manganese(V) complexes in MeCN/HO 9:1. The oxidation follows an overall second-order kinetics, first-order each in sulfide and oxo(salen)manganese(V) complex. Electron-attracting substituents in the sulfide and electron-releasing substituents in salen of the oxo(salen)manganese(V) complexes reduce the rate of oxidation. A Hammett analysis of the rate constants for the oxidation of 4-substituted phenyl phenyl sulfides gives a negative  value ( = -2.29) indicating an electron-deficient transition state. The log k value observed in the oxidation of each 4-substituted phenyl phenyl sulfides by substituted oxo(salen)manganese(V) complexs also correlate with Hammett  constants, giving positive  value. The substituent-, acid-, and solvent-effect studies indicate direct O-atom transfer from the oxidant to the substrate in the rate-determining step. <#LINE#> @ @ Kaushik R.D., Arya R.K. and Kumar S., Periodate oxidation of aromatic amines - Kinetics and mechanism of oxidation of N – ethylaniline in acetone – water medium, Asian. J. Chem., 12(4), 1229 (2000) @No $ @ @ Panigrahi G.P. and Mishra P.K., Kinetics and Mechanism of Os(VIII) Catalyzed Oxidation of Cyclohexanone by Alkaline Periodate, Indian. J. Chem. 16A(9), 762 (1978) @No $ @ @ Katsuki T., Mn-salen catalyst, competitor of enzymes, for asymmetric epoxidation, J. Mol.Catal. A: Chem.,113, 87 (1996) @No $ @ @ Groves J.T. and Nemo T.E., Epoxidation reactions catalyzed by iron porphyrins, Oxygen transfer from iodosylbenzene, J. Am. Chem. Soc.,105, 5786 (1983) @No $ @ @ Sugimoto H., Tung H.C. and Sawyer D.T., The formation, characterization, and reactivity of the oxene adduct of [tetrakis(2,6-dichlorophenyl) porphinato] iron (III) perchlorate in acetonitrile, Model for the reactive intermediate of cytochrome P-450, J. Am. Chem. Soc., 110,2465 (1988) @No $ @ @ Mohajer D. and Tangestanninejad S., Efficient olefin epoxidation with tetrabutylammonium periodate catalyzed by manganese porphyrin in the presence of imidazole, Tetrahedron Lett., 6, 945 (1994) @No $ @ @ Curci R., Advances in Oxygenated Processes, edited by A.L. Baumstark (Greenwich Press) (1990) @No $ @ @ Ballistreri F.P., Thmaselli G.A., Toscano R.M., Bonchio M., Conte V., and Di Fura F., The relative reactivity of thioethers and sulfoxides toward oxygen transfer reagents: the case of dioxiranes, Tetrahedron Lett.,35, 8041 (1994) @No $ @ @ Mirkhani V., Tangestaninejad S., Moghadam M. and Moghbel M., Cytochrome P-450 dependent monooxygenases model system: rapid and efficient oxidation of primary aromatic amines to azo derivatives with sodium periodate catalyzed by manganese(III) Schiff base complexes, Bioorg. Med. Chem., 12, 4673 (2004) @No $ @ @ Mohajer D. and Tangestaninejad S., Efficient catalytic epoxidation of alkenes by a manganese porphyrin and periodate in the presence of imidazole, J. Chem. Soc. Chem. Commun., 240 (1993) @No $ @ @ Johnson C.R. and  McCants D., The Stereochemistry of Oxidation at Sulfur. Oxidation of 4-Substituted Thianes to Sulfoxides, J. Am. Chem. Soc. 87, 1109 (1965) @No $ @ @ Ruff F. and Kucsman A., Mechanism of the oxidation of sulphides with sodium periodate, J. Chem. Soc. Perkin Trans., 2, 683 (1985) @No $ @ @ Chellamani A. and Harikengaram S., Kinetics and mechanism of (salen)MnIII-catalysed oxidation of organic sulfides with sodium hypochlorite, J. Phys. Org. Chem.,16,589 (2003) @No $ @ @ Srinivasan K., Michaud P. and Kochi J.K., Epoxidation of olefins with cationic (salen) manganese (III) complexes, The modulation of catalytic activity by substituents, J. Am. Chem. Soc.,108, 2309 (1986) @No $ @ @ Meunier B., De carvalho M.E., Bortolini O. and Momentea M., Proximal effect of the nitrogen ligands in the catalytic epoxidation of olefins by the sodium hypochlorite/manganese(III) porphyrin system, Inorg. Chem.,27, 161 (1988) @No $ @ @ Srinivasan C., Chellamani A. and Rajagopal S., Mechanism of the oxidation of alkyl aryl and diphenyl sulfides by chromium(VI), J. Org. Chem.50, 1201 (1985) @No $ @ @ Baciocchi E., Intini D., Piermattei A., Roh C. and Ruzziconi R., Product and Kinetic Study of the Oxidation of Thioethers by Cerium(IV) Ammonium Nitrate in Acetic Acid, Gazz. Chim. Ital., 119, 649 (1989) @No $ @ @ Balakumar S., Thanesekaran P., Rajagopal S. and Ramaraj R., Electron transfer reactions of iron (III) - polypyridyl complexes with organic sulphides, Tetrahedron.,51, 4801 (1995) @No $ @ @ Miller A.E., Bischoff J.J., Bizub C., Luminnoso P. and Smiley S., Electronic and Steric Effects in  Oxidations by Isoalloxazine 4a-Hydroperoxides, J. Am. Chem. Soc.,108,7773 (1986) @No $ @ @ Oae S., Watanabe Y. and Fujimori K., Biomimetic oxidation of organic sulfides with TPPFe(III)Cl/imidazole/ hydrogen peroxide, Tetrahedron Lett., 23, 1189 (1982) @No $ @ @ March J., Advanced Organic Chemistry (4th edn), Wiley : New York,  251 (1992) @No $ @ @ Vyas V.K., Jalani N., Kothari S. and Banerji K.K., Kinetics and mechanism of the oxidation of organic sulfides by pyridinium hydrobromide perbromide, J. Chem. Res., 370 (1996) @No $ @ @ Srinivasan C., Rajagopal S. and Chellamani A., Mechanism of picolinic-acid-catalysed chromium(VI) oxidation of alkyl aryl and diphenyl sulphides, J. Chem. Soc. Perkin Trans., 2,1839 (1990) @No $ @ @ Sevvel R., Rajagopal S., Srinivisan C., Alhaji N.M.I. and Chellamani A., Mechanism of Selective Oxidation of Organic Sulfides with Oxo(salen)chromium(V) Complexes, J. Org. Chem.,65, 3334 (2000) @No $ @ @ Erdik E. and Eroglu F., Kinetics and mechanism of the C-S coupling reactions of aryl Grignard reagents with aryl arenesulfonates, Cent. Eur. J. Chem.,6, 237 (2008) @No $ @ @ Koh H.J., Kang S.J. and Kevil D.N., Correlation of the Rates of Solvolysis of Diphenylthiophosphinyl Chloride Using an Extended form of the Grunwald-Winstein Equation, Bull. Korean. Chem. Soc.,29, 1927 (2008) @No $ @ @ Ganesan T.K., Rajagopal S. and Bharathy J.B., Comparative Study of Chromium(V) and Chromium(VI) Oxidation of Dialkyl Sulfides, Tetrahedron., 56, 5885 (2000) @No $ @ @ Diwya Pushpa I. and Ramachandrppa R., Oxidation of Tranexamic Acid by Bromamine – T in HCl Medium Catalyzed by RuCl: A Kinetic and Mechanistic Approach, Res.J.Chem.Sci. 2(7), 15 (2012) @No $ @ @ Kumar G.M. and Rajput Surendra K., Uncatalysed Oxidation of Dextrose by Cerium(IV) in Aqueous Acidic Medium-A Kinetic and Mechanistic Study, Res.J.Chem.Sci., 2(11), 60 (2012) @No 
<#LINE#>Uptake of Toxic Hexavelantchromium Element from Aqueous Solution by Annona Squamosa Carbon<#LINE#>Renukadevi@C.,T.@Santhi<#LINE#>36-43<#LINE#>5.ISCA-RJCS-2013-016.pdf<#LINE#> Department of Chemistry, Gandhi Polytechnic College, Tamil Nadu, INDIA @ Department of Chemistry Karpagam University, Coimbatore-641 014, INDIA<#LINE#>31/1/2013<#LINE#>6/2/2013<#LINE#> Annona Squamosa was used for the preparation of activated carbon for the removal of toxic elements like chromium (V1) from waste water. The effects of concentration of pH, temperature, adsorption capacity have been investigated. Adsorption capacity of Annona Squamosa activated carbon was showed highest value around pH=3. A direct proportionality between the percentages of Cr (V1) removal (86.11%) requested within 15 min from start of every experiment .The Adsorption kinetic data were tested using pseudo-first order, pseudo-second order, and Elovich and intra-particle diffusion models. Kinetics studies showed that the adsorption followed a pseudo second order reaction of Cr(V1) followed pseudo second order kinetics equations and fits the Langmuir, Freundlich , Tempkin and Elovich equation well Activated carbon developed from Annona Squmosa seed can be highly efficient option for Cr(V1) from  wastewater showed better removal percentage of Cr (V1)<#LINE#> @ @ Santhi T., Manonmani S., Smitha T., Removal of malachite green from aqueous Solution by activated Carbon, prepared fromAnnona Squmosa Seed by adsorption theApril-June 20102(2), Sparks, D.L; CRC Press,  Boca Raton (1986) @No $ @ @ Ali Huddin and Irvan Dahlan, Comparative study on characterization of Malaysian Palm oil mill Effluent, Research Journal of chemical science, 2(12), 15 (2012) @No $ @ @ Chandra Sekhar Reddy L., Ramana Reddy K.V., Sumedh K. Humane and Damodaram B., Accumulation of Chromium in Certain plant Species Growing on Mine Dump from Byrapur, Karnataka, India, Res.J.Chem. Sci.,2(12), 17-20 (2012) @No $ @ @ Mohammed S.S., Batu M.A. and Mohammed M.B., Analysis of Cr in Dumpsite Soil Samples Using AAS and EDXRF Techniques, Res. J. Chem. Sci.,2(12), 65-68 (2012) @No $ @ @ Shaikh Parveen R. and Bhosle Arjun, Heavy Metal Contamination in Soils near Siddheshwar Dam Maharashtra, B., Res. J. Chem. Sci., 3(1), 6-9 (2013) @No $ @ @ Al-Sultani Kadhim F. and Al-Seroury F.A., Characterization the Removal of Phenol from Aqueous Solution in Fluidized Bed Column by Rice Husk Adsorbent, Res. J. Recent Sci.,1(ISC-2011), 145-151 (2012) @No $ @ @ Sharifirad M., Koohyar F., Rahmanpour S.H. and Vahidifar M., Preparation of Activated Carbon from Phragmites Australis:Equilibrium Behaviour Study, Res.J.Recent Sci.,1(8), 10-16 (2012) @No $ @ @ Santhi T., Manonmani S. and Smitha T., Kinetics and Isotherm Studies on Cationic Dyes Adsorption onto Annona Squmosa Seed Activated Carbon International,Journal ofEngineering Science and Technology, 2(3), 287- 295 (2010) @No $ @ @ Tariq S. Najm and Suhad A. Yassin Removal of Cr (V1) from Aqueous Solution Using Modified Pomegranate   Peel: Equilibrium and Kinetic Studies, E-Journal of Chemistry, 6(S1) 29-S142 (2009) @No $ @ @ Veli S. and Pekey B., Removal of Copper from aqueous solution by ion exchange resins, Fresenius Environ. Bull. 13, 244-250 (2004) @No $ @ @ Zhenhuttu, Huichen Feng Ji and Shoujun Yuna, Removal of Congo red from aqueous solution by cattail root, Journal of Hazardous materials, 173, 292-297 (2010) @No $ @ @ Vimonse V., Lei S.M., Jin B., Chad C.W.K. and Saint C., Kinetic study and equilibrium isotherm analysis of Red Adsorption by clay materials, Chem. Eng. J., 48, 354-364(2009) @No $ @ @ Altinisik A., Gur, Emel and Seki Yoldas, A natural sorbent, Luffa cylindrical for the removal of a model basic dye, J. Hazard, Mater, dio, 10, 1016 (2010) @No $ @ @ Bulut E., Ozacar M. and Sengil A.I., Adsorption of malachite green onto bentonite; equilibrium and kinetic   studies and process design, Micropor. Mesopor, Mater, 115, 234-246 (2008) @No $ @ @ Ashly Leena Prasad, Santhi T. and Manonmani S., Recent developments in preparation of activated carbons by   microwave: study of residual error, Arabian journal of chemistry xxx, xxx, xxx, (2011) @No $ @ @ Langmuir I., JAM Chem.Soc., 38, 2221 (1916) @No $ @ @ Dogan M., Alkan M., Onganer Y., Water, Air, Soil Pollut, 120, 229 (2000) @No $ @ @ Kinniburgh D.G., Environ.Sci.Technol., 20, 895 (1986) @No $ @ @ Longhinitti E., Pozza F., Furlan L., Sanchez M.D.N.D., Klug M., Laranjeira M.C.M., Favere, V.T. J Brazil. Chem. Soc, , 435 (1998) @No $ @ @ Aharoni C., Sparks, D.L., Rate of Soil Chemical processes, Soil science Society of America, Madison; WJ (1991) @No $ @ @ Aharoni C., Ungarish, M.J.Chem.Soc. Farady Trans73,456 (1977) @No $ @ @ Pearce C.I., Lioyd J.R., Guthrie I.T., Dyes Pigments,58,179 (2003) @No $ @ @ Dubinin M.M., Chem.Rev. 60, 235 (1960) @No $ @ @ Dubinin M.M., Zhurnal Fizicheskoi Khimii 39, 1305 1965) @No $ @ @ Radush Kevich, L.V. Zhurnal Fizicheskoi Khimii, 23, 1410(1949) @No $ @ @  Kundu S., Gupta A.K., colloid Surf. A: Physico chem. Eng. Aspects,273, 121 (2006) @No $ @ @ Lagergren, S. Handlingar 24, 1 (1898) @No $ @ @ Ho Y.S., McKay G., Wase, D.A.J, Faster, C.F.Adsorp.Sci.Technol, 18, 639 (2000) @No $ @ @  Chien S.H., Clayton, W.R. Soil Sci. Soc. Am. J., 44, 265 (1980) @No $ @ @  Zeldowitch J., Acta Physicohim URSS,, 364 (1934) @No $ @ @ Weber W.J., Morris, J.C.JSanity Eng.D, V, Am.Soc.Civil Eng, 89, 31 (1963) @No $ @ @ Srinivasan K., Balasubramanian N., RamaKrishnan, T.V.Indian .Environ.Health,30, 376 (1988) @No $ @ @ Coswami S. and Ghosh U.C., Water SA31, 597-602 ASCE89(SA2), 31-59, (2005) (1963) @No $ @ @  Ho Y.S., Water Res37, 2323-2330 (2003) @No $ @ @ Crini G.Peindy HN, Gimbert F and Robert C, sep PutifTechol), 53, 97-110 (2007)  @No $ @ @ Kameed B.H., Tan A.W., Ahmad A.L., Hazard J., mater164 1316-1324 (2009) @No
<#LINE#>Electrosynthesis and Characterization of CdSeHgTl Thin Films<#LINE#>R.K.@Pathak<#LINE#>44-47<#LINE#>6.ISCA-RJCS-2013-021.pdf<#LINE#> Department of Chemistry, Government MLB College, Indore, MP, INDIA<#LINE#>7/2/2013<#LINE#>25/3/2013<#LINE#> Tl containing CdSeHg films have been electrosynthesised at – 0.600 V vs SCE on titanium substrate from the aqueous solution. Electrochemical properties of the films were investigated in 1/I- redox solution. Films were found to be p-type conductivity with charge carrier level 1025. The carrier concentration and flat band potential of the film were determined from capacitance measurements. The films were characterized with scanning election microscopy (SEM) combined with energy dispersive X-ray analysis (EDAX) system. The corrosion characteristics of the films have been studied by polarization technique. The inhibitor inhibits corrosion even in trace amount. This is the study to investigate the effect of thallium concentration on the composition, capacitance, photo activity, morphology and corrosion parameters of the CdHgSeTl films electrosyntesised by electrodeposition. <#LINE#> @ @ Durairajan A. and Haran B.S., Development of a new electrodeposition process for plating of Zn-Ni-X alloys, J. electrochem. Soc.,147(12), 4507 (2000) @No $ @ @ Bhahada K.C. and Tripathi B., Formation of ZnSe by stacked elemental layer method, Chalcogenide let., 5(7), 137-142 (2008) @No $ @ @ Mahalingam T. and Kathalingam A., Studies of electrosynthesised zinc selenide thin films, J. New  mat. Electochem. Sys. 10, 15-19 (2007) @No $ @ @ Mishra S.D. and Singh K., Electrodeposition of ZnSe: colloidal HgS composit and their photoelectrochemical characterization, Solar Energy mat. and solar cells, 93,1202-1207 (2009) @No $ @ @ Singh K. and Pathak R.K., Electrosynthesis and impedance studies on Zinc Selenide., Electrochimica Acta, 39 (18), 2691-2697 (1994) @No $ @ @ Pathak R.K. and Mohan C., Study of electrosynthesis and characterization of In doped ZnSe thin films, Mat. Sc. Res. Ind., 5(2), 477-480 (2008) @No $ @ @ Ellis A.B. and Kwiser S.W., Advance in chemistry, Solid state chemistry of energy conversion and storage, eds Govdenongh J.B. and whittingham, (1977) @No $ @ @ Wanand A., Electrochemical technology, Theory and practice., eds Lubomyr T.R., (1987) @No $ @ @ Gerishar H. Physical chemistry, advance Treatise, eds. Eyring H. Henderson D. and Jost w., Acad. Press, New York (1970) @No $ @ @ Barote M.A. and Yadav A., Chemical bath deposited PbSe thin films: optical and electrical transport properties., Res. J. Chem Sc., 2(1), 15-19 (2012) @No $ @ @ Bard A.J. and Faulkner L.R., Electrochemical methods, Fundamental Applications, John Wiley and Sons, NY (2000) @No $ @ @ Bockris J.O.M., Reddy A.K.N., Modern Electrochemistry, Plennum Press, NY (2000) @No $ @ @ Fontana M.G. and Stachle R.W., Advance corrosion science and technology, Plennuum  Press (1970) @No $ @ @ Princeton Applied Research Corporation, Copyright, MNLA, 219(A) (1986) @No $ @ @ Memming R. and Kelly J., Photochemical conversion and storage of solar energy, Academic press, NY (1998) @No $ @ @ Bregmann J.J., Corrosion Inhibitor, Macn, NY (1963) @No 
<#LINE#>Biosorption of Chromium (VI) from Industrial Effluent using Neem Leaf Adsorbent<#LINE#>Gopalakrishnan@S.,Kannadasan@T,S.@Velmurugan,Muthu@S.,VinothKumar@P<#LINE#>48-53<#LINE#>7.ISCA-RJCS-2013 031.pdf<#LINE#>Department of Chemical Engineering, Coimbatore Institute of Technology, Coimbatore –14, Tamil Nadu, INDIA<#LINE#>26/2/2013<#LINE#>11/3/2013<#LINE#> Industrial water pollution is a potential threat to human health mainly because of the non-biodegradable, hazardous heavy metals. Among these heavy metals chromium is of considerable concern. Various methods adopted for removal of heavy metals include chemical precipitation, membrane separation, ion exchange and adsorption. In case of adsorption, the generally used adsorbents like activated carbon, silica, alumina, etc. are expensive. This has prompted the use of natural materials as adsorbents in order to develop cheaper alternatives, which can be disposed off without regeneration due to their lower cost. Azadirachta indica leaf powder is tried for the removal of chromium. The newly developed adsorbents should be as effective as the conventional ones. Hence in the present work, Azadirachta indica (Neem) leaf powder is studied for their adsorptive capacity to remove chromium (VI) from aqueous solution. The equilibrium studies are systematically carried out in a batch process covering various process parameters that include agitation time, adsorbent dosage, temperature and initial concentration of chromium. The adsorption behavior is finding to follow the Freundlich Adsorption Isotherm. <#LINE#> @ @ Donmez G. and Aksu Z., Removal of chromium (VI) from wastewaters by Dunaliella species, Process Biochemistry, 38(5), 751–762 (2002) @No $ @ @ Hu Z., Lei L., Li Y. and Ni Y., Chromium adsorption on high performance activated carbon from aqueous solution, Separation and Purification Technology, 31(1), 13–18 (2003) @No $ @ @ Lotfi M. and Adhoum N., Modified activated carbon for the removal of copper, zinc, chromium and cyanide from wastewater, Separation and Purification Technology, 26(2–3), 137–146 (2002) @No $ @ @ Rao M.M., Ramesh A., Rao G.P.C. and Seshaiah K., Removal of copper and cadmium from the aqueous solutions by activated carbon derived from Ceibapentandra hulls, J. Hazard. Mater, 129, 123-129 (2006) @No $ @ @ Sharma D.C. and Forster C.F., Removal of hexavalent chromium using sphagnum moss peat, Water Research, 27, 1201–1208 (1993) @No $ @ @ Ozer A., Altundogan H.S., Erdem M. and Tunmen F., A study on the Cr (VI) removal from aqueous solutions by steel wool, Environmental Pollution, 97(1–2), 107–112 (1997) @No $ @ @ Mauri R., Shinnar R., Amore M.D., Giordano P. and Volpe A., Solvent extraction of chromium and cadmium from contaminated soils, American Institute of Chemical Engineers Journal (AIChE), 47(2), 509512 (2001) @No $ @ @ Padilla A. and Tavani E.L., Treatment of an industrial effluent by reverse osmosis, Desalination, 129(1–3), 219–226 (1999) @No $ @ @ Dakiky M., Khami A., Manassra A. and Mer’eb M., Selective adsorption of chromium (VI) in industrial wastewater using low cost abundantly available adsorbents, Advances in Environmental Research, 6(4), 533–540 (2002) @No $ @ @ Panday K.K., Prasad G. and Singh V.N., Removal of chromium from aqueous solution by adsorption on fly ash wollostonite, Journal of Chemical Technology and Biotechnology,  34, 367–374 (1984) @No $ @ @ Srivastava S.K., Tyagi R. and Pant N., Adsorption of heavy metal ions on carbonaceous material developed from the waste slurry generated in local fertilizer plant, Water Research, 23, 1161–1165 (1989) @No $ @ @ Namasivayam C. and Rangnathan K., Waste Fe (III)/Cr (III) hydroxide adsorbent for the removal of Cr (VI) from aqueous solution and chromium plating industry wastewater, Environmental Pollution, 82, 255–261(1993) @No $ @ @ Patnaik L.N. and Das C.P., Removal of hexavalent chromium by blast furnace flue dust, Indian Journal of Environmental Health, 37, 19–25 (1995) @No $ @ @ Selvaraj K., Chandramohan V. and Pattabhi S., Removal of Cr (VI) from solution and chromium plating industry wastewater using photo film waste sludge, Indian Journal of Chemical Technology, 18, 641–646 (1997) @No $ @ @ Rawat N.S. and Singh C.D., Removal of Cr (VI) on bituminous coal’, Asian Environment, 14, 30–41 (1992) @No $ @ @ Sharma D.C. and Forster C.F., A preliminary examinations into the adsorption of hexavalent chromium using low cost adsorbents, Bio resource Technology, 47, 257–264 (1994) @No $ @ @ Tan W.T., Ooi S.T. and Lee C.K., Removal of Cr (VI) from solution by coconut husk and palm pressed fiber, Environmental Technology, 14, 277 (1993) @No $ @ @ Dikshit V.P., Removal of chromium (VI) by adsorption using sawdust’, National Academy of Science Letters, 12(12), 419–421 (1989) @No $ @ @ Selvaraj K., Manonmani S. and Pattabhi S., Removal of hexavalent chromium using distillery sludge, Bio resource Technology, 89(2), 207–211 (2003) @No $ @ @ Veeraswamy R., Venkateswaren V., Kulandaivelu A.R., Basic Principles of Practical Chemistry, S. Chand  Publisher (2007) @No $ @ @ Febrianto J. Kosasib A.N. Sonarso J., Ju Y.H., Indraswati N. and Ismadji S., Equilibrium and kinetic studies in adsorptions of heavy metals using biosorbents, A summaruy of recent studies, J. Hazard. Matter,162, 616–645 (2008) @No $ @ @ Reddy D.H.K., Seshaiah K., Reddy A.V.R., M.M., Wang M.C., Bio sorption of pb2+ from aqueous solution by moringa oleifera bark: Equilibrium and kinetics studies, J. Hazard matter,174, 831–838 (2010) @No 
<#LINE#>Synergistic Effect of Triisopropanolamine in Aqueous Solution by Sodium St–Zn2+ System<#LINE#>BrightsonArul@JacobY,Sayee@KannanR.,Jeyasundari@J<#LINE#>54-58<#LINE#>8.ISCA-RJCS-2013-032.pdf<#LINE#> Department of Chemistry, NMSSVN College, Madurai-625019, Tamilnadu, INDIA @ Department of Chemistry, Thiagarajar College, Madurai-625009, Tamilnadu, INDIA<#LINE#>27/2/2013<#LINE#>8/3/2013<#LINE#> The aim of this present work is to study the corrosion behavior of mild steel in aqueous solution containing 60ppm Cl in the presence of TIPA (Triisopropanolamine)-Zn2+-ST (Sodium Tungstate). Weight loss study has been employed to evaluate the inhibition efficiency of this system. It was found that the inhibition efficiency of TIPA-Zn2+   was improved from 63% to 97% by the addition of 150 ppm of ST. The corrosion rate was calculated in the presence and absence of inhibitor. The protective film consists of Fe2+-Wo2-, Fe2+ - TIPA complex on anodic site and Zn (OH) complex at cathodic site. A mechanism for the inhibition of corrosion is proposed based on the above results.  TIPA and Sodium tungstate (NaWO) as a corrosion inhibitors of mild steel in aqueous solution containing 60 ppm Cl  was investigated by potentiodynamic polarization, and electrochemical impedance spectroscopy (EIS). The surface of the specimen has been examined using, scanning electron microscope <#LINE#> @ @ Noreen Antony H., Benita Sherine and Susai Rajendran, Investigation of the inhibiting effect of Carboxymethylcellulose-zn2+ system on the corrosion of carbon steel in neutral chloride solution, The Arabian Journal for Science and Engineering,35, 2A (2010) @No $ @ @ Vhlig H.H. and Revie R.W., Corrosion and corrosion control, An Introduction to Corrosion Science and Engineering, Newyork, John Wiley and sons.Inc., 425, 1985 @No $ @ @ Gredhil W.E. and Peitjel T.C.J., The Hand book of Environmental Chemistry, Springer – Verlag, In. Hatzingeer (Ed) Berlin, Pan TF, 3, (1992) @No $ @ @ L. Garreric(editor), Corrosion in the petro chemical Industry, ASM international USA (1995) @No $ @ @ Negishi A., Muraoka T., Maeda T., Takeuchi F., Kanao T., Kamimura K. and Sugio T., Growth Inhibition by Tungsten in the Sulfur-Oxidizing Bacterium Acidithiobacillus Thiooxidans, Bioscience, Biotechnology and Biochemistry.,69, 2073–2080 (2005) @No $ @ @ Wang X.K., Luo G.Q. and Li N., Vapor Phase Corrosion Inhibitors Used for Drawn-and -Ironed (DI) Material, Corrosion and Protection., 26, 189–191 (2005) @No $ @ @ Xu Q.J., Zhou G.D., Wang H.F. and Cai W.B., Electrochemical Studies of Polyaspartic Acid and Sodium Tungstate as Corrosion Inhibitors for Brass and Cu30Ni Alloy in Simulated Cooled Water Solutions, AntiCorrosion Methods and Materials., 53, 207–211 (2006) @No $ @ @ Abdallah M., El-Etre A.Y., Soliman M.G. and Mabrouk E.M., Some Organic and Inorganic Compounds as Inhibitors for Carbon Steel Corrosion in 3.5 Percent NaCl Solution,  Anti-Corrosion Methods and Materials, 53,118–123 (2006) @No $ @ @ Amin M.A., Hassan H.H. and Abd El Rehim S.S., On the Role of NO Ions in Passivity Breakdown of Zn in Deaerated Neutral Sodium Nitrite Solutions and the Effect of Some Inorganic Inhibitors, Potentiodynamic Polarization, Cyclic Voltammetry, SEM and EDX Studies, Electrochimica Acta,53, 2600–2609 (2008) @No $ @ @ Negishi A., Muraoka T., Maeda T., Takeuchi F., Kanao T.,  Kamimura K. and Sugio T., Growth Inhibition by Tungsten in the Sulfur-Oxidizing Bacterium Acidithiobacillus Thiooxidans, Bioscience, Biotechnology and Biochemistry.,69, 2073–2080 (2005) @No $ @ @ Srivastava K. and Srivastava P., Studies on Plant Materials as Corrosion Inhibitors, Br Corrrs J.,  16, 221 (1981) @No $ @ @ Agnesia Kanimozhi S. and Rajendran S., Inhibitive Properties of Sodium Tungstate Zn2+ System and its Synergism with HEDP, Inter. 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V. suppl.,9, 745 (1990) @No $ @ @ Felicia Rajammal Selvarani, Santhamadharasi S., Wilson Sahayaraj J., John Amalraj A. and Susai Rajendran, Bull.Electrochemistry, 20,561-566(2004) @No $ @ @ Sangeetha M., Rajendran S., Sathiyabama J., Krishnaveni A., Shanthy P., Manimaran N. and Shyamaladevi B., Corrosion Inhibition by an Aqueous Extract of Phyllanthus Amarus, Portugaliae Electrochimica Acta.,29 (6), 429– 444 (2011) @No $ @ @ Manivannan M. and Rajendran S., Corrosion Inhibition of carbon steel by Succinic acid – Zn2+ system, ResearchJournal of Chemical Sciences, 1(8), 42-48(2011) @No $ @ @ Xu Yang, Fu Sheng Pan and Ding Fei Zhang, A study on corrosion inhibitor for magnesium alloy, Mat. Sci. Forum,610-613, 920-926 (2009) @No $ @ @ Gogoi P.K. and Barhai B., Corrosion Inhibition of carbon steel in open recirculating cooling water system of Petroleum refinery by a multi-component blend containing zinc (11) diethyldithio carbamate, Indian J. Chem.Technology, 17,291-295(2010) @No $ @ @ Hamdy A., Farag A.B., EL – Bassoussi A.A., Salah B.A. and Ibrahim O.M., Electrochemical behavior of brass Alloy in different saline media: Effect of BenzotriazoleWorld App. Sci. Journal, 8,565-571(2010) @No $ @ @ Weihua Li, Lichao Hu, Shengtao Zhang and Baorong Hou, Effects of two fungicides on the corrosion Resistance of copper in 3.5% Nacl solution under various conditions, Corrosion Sci., 53,735-745(2011) @No 
<#LINE#>Silicotungstic Acid in Organic Synthesis: Synthesis of 1, 5-Benzodiazepines and &#946;-Amino Carbonyl Compounds<#LINE#>JaspreetKaur@Rajput, Gagandeep@Kaur<#LINE#>59-64<#LINE#>9.ISCA-RJCS-2013-033.pdf<#LINE#> Department of Chemistry, Dr. B. R. Ambedkar National Institute of Technology, Jalandhar - 144011, INDIA<#LINE#>27/2/2013<#LINE#>7/3/2013<#LINE#> An efficient methodology, employing silicotungstic acid (STA) as catalyst leads to synthesis of 1, 5-benzodiazepines and amino carbonyl compounds, employing condensation reaction of o-phenylenediamine with ketones and one pot three component Mannich reaction at room temperature under solvent free conditions in good to excellent yields. The synthetic protocol offers a novel and improved modification for the synthesis of 1, 5-benzodiazepines and -amino carbonyl compounds in terms of mild reaction conditions and clean reaction profiles, high yields and a simple workup procedure. They are characterised by IR and H NMR spectroscopy.<#LINE#> @ @ Smalley R.K., In Comprehensive Organic Chemistry; Oxford:Pergamon, 1979 @No $ @ @  Landquist J.K., In Comprehensive Heterocyclic Chemistry; Oxford:Pergamon, 1984 @No $ @ @ Essaber M. Baouid A. Hasnaoui A. Benharref A. and Lavergne J.P., Synthesis of New Tri- and Tetraheterocyclic Systems: 1,3-Dipolar Cycloaddition of Nitrilimines on 2,7-Dimethyl-4-Phenyl-3H-1,5-Benzodiazepine, Synth. Commun., 28, 4097-4104 (1998) @No $ @ @ .Bennamane N. Kaoua R. Hammal L. and Nedjar-Kolli B., Synthesis of new amino-1,5-benzodiazepine and benzotriazole derivatives from dimedone, Org. Commun., , 62-68 (2008) @No $ @ @ Boudina A. Baouid A. Hasnaoui A. and Essaber M., Synthesis of New Tetraheterocyclic Systems by the Mixed Condensation Reactions on [1,2,4]Triazolo[4,3a][1,5]benzodiazepines, Synth. Commun., 36, 573-579 (2006) @No $ @ @ Xu J. X. Wu H. T. and Jin S., Cycloaddition of benzoheteroazepine II Reactions and conformations of cycloadducts on 1, 5-benzothiazepines and 1,5-benzodiazepines with nitrile imine and nitrile oxides, Chin. J. Chem. 17, 84-91 (1999) @No $ @ @ Nabih K. Baouid A. Hasnaoui A. and Kenz A., Highly Regio- and Diastereoselective 1,3-Dipolar Cycloaddition of Nitrile Oxides to 2,4-Dimethyl-3H-1,5-Benzodiazepines: Synthesis of Bis[1,2,4Oxadiazolo][1,5]Benzodiazepine Derivatives, Synth. Commun. 34, 3565-3572 (2004) @No $ @ @ Reddy K. V. V. Rao P. S. and Ashok D., A Facile Synthesis of 2-Benzoyl-6-Hydroxy-3-Methyl-5-(2-Substituted-2,3-Dihydro-1-1,5-Benzodiazepin-4-YLBenzo[]Furans, Synth. Commun., 30, 1825-1836 (2000) @No $ @ @ Stahlofen P. and Ried W., Über heterocyclische Siebenringsysteme, V. Umsetzung von -phenylendiamin mit -ungesättigten carbonylverbindungen, Chem. Ber.90, 815-824 (1957) @No $ @ @ Ried W. and Torinus E., Über heterocyclische siebenringsysteme, X. 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Commun., 67-70 2005) @No $ @ @ Balakrishna M. S. and Kaboudin B., A simple and new method for the synthesis of 1,5-benzodiazepine derivatives on a solid surface, Tetrahedron Lett., 42, 1127-1129 (2001) @No $ @ @ Kaboadin B. and Navaee K., Alumina/phosphorus pentoxide (APP) as an efficient reagent for the synthesis of 1,5-benzodiazepines under microwave irradiation,Heterocycles, 55, 1443-1446 (2001) @No $ @ @ Kuo C. W. More S. V. and Yao C. F., NBS as an efficient catalyst for the synthesis of 1,5-benzodiazepine derivatives under mild conditions, Tetrahedron Lett. 47, 8523-8528 2006) @No $ @ @ Yadav J.S. Reddy B.V.S. Praveen Kumar S. and Nagaiah K., Indium(III) bromide: A novel and efficient reagent for the rapid synthesis of 1,5-benzodiazepines under solvent-free conditions, Synthesis, 480-484 (2005) @No $ @ @ De S. K. and Gibbs R. A., Scandium(III) triflate as an efficient and reusable catalyst for synthesis of 1,5-benzodiazepine derivatives, Tetrahedron Lett., 46, 1811-1813 (2005) @No $ @ @ Heravi M. M. Derikvand F. Ranjbar, L. and Oskooie H. A., Kaolin: A recyclable catalyst for the synthesis of 1,5-benzodiazepines, Heteroatom Chemistry, 19, 215-217 2008) @No $ @ @ Gao S. T. Liu W. H. Ma J. J. Wang C. and Liang Q., NbCl as an Efficient Catalyst for the Synthesis of 1,5-Benzodiazepine Derivatives, Synth. Commun., 39, 3278-3284 (2009) @No $ @ @ Arend M. Westermann B. and Risch N., Modern Variants of the Mannich Reaction, Angew. Chem. Int. Ed., 37, 1044-1070 (1998) @No $ @ @ Marques M. M. B., Catalytic Enantioselective Cross-Mannich Reaction of Aldehydes, Angew Chem. Int. Ed., 45348-352 (2006) @No $ @ @ Muller R. Goesmann H. and Waldmann H., Phthaloylamino Acids as Chiral Auxiliaries in Asymmetric Mannich-Type Reactions, Angew Chem. Int. Ed., 38, 184-187 (1999) @No $ @ @ Bohme H. and Haake M., Advances in Organic Chemistry; New York:John Wiley and Sons, 1976 @No $ @ @ (a) Dziedzic P. Ibrahem I. and Cordova A., Direct catalytic asymmetric three-component Mannich reactions with dihydroxyacetone: enantioselective synthesis of amino sugar derivatives, Tetrahedron lett., 49, 803-807 (2008) (b) Hayashi Y. Urushima T. Aratake S. Okano T. and Obi K., Organic Solvent-Free, Enantio- and Diastereoselective, Direct Mannich Reaction in the Presence of Water ,Org. Lett., 10, 21-24 (2008) (c) Khan A.T. Pravin T. and Choudhary L.H., Bromodimethylsulfonium Bromide Catalyzed Three-Component Mannich-Type Reactions, Eur. J. Org. Chem., 834-839 (2008)  (d) Bigdeli M.A. Nemati F. and Mahdavina G.H., HClO–SiO catalyzed stereoselective synthesis of -amino ketones via a direct Mannich-type reaction Tetrahedron Lett., 48, 6801-6804 2007) (e) Guo Q. X. Liu H. Guo C. Luo S. W. Gu Y. and Gong L. Z., Chiral Brønsted Acid-Catalyzed Direct Asymmetric Mannich Reaction, J. Am. Chem. Soc., 129, 3790-3791 (2007)(f) Wang R. Li B. G. Huang T. K. Shi L. and Lu X. X., NbCl-Catalyzed one-pot Mannich-type reaction: three component synthesis of -amino carbonyl compounds, Tetrahedron Lett., 48, 2071-2073 (2007) (g) Wu H. Shen L. Y. Fan Y. Zhang P. Chen C. F. and Wang W. X., Stereoselective synthesis of -amino ketones via direct Mannich-type reaction catalyzed with silica sulfuric acid, Tetrahedron, 632404-2408 (2007)  (h) Cheng L. Wu X. and Lu Y., Direct asymmetric three-component organocatalytic anti-selective Mannich reactions in a purely aqueous system, Org. Biomol. Chem., , 1018-1020 (2007) @No $ @ @ (a)Rajput J. Singh B. And Singal K. K., One-pot synthesis of pyrrolo-[3,4-d]isoxazoline-4,6-diones via nitrile oxides, Chemistry of Heterocyclic Compounds, 45, 361-364 (2009) (b) Kaur J. Singh B. and Singal K. K., Huisgen reaction of nitrile oxides and nitrile imines leading to isoxazoline and pyrazole-4,6-diones, Chemistry of Heterocyclic Compounds, 42, 818-822 (2006) @No $ @ @ (a) Misono M. Ono L. Koyano G. and Aoshima A., Heteropolyacids. Versatile green catalysts usable in a variety of reaction media, Pure Appl. Chem., 72, 1305-1311 2000) (b) Pope M. T. and Mullar A., Polyoxometalates: From Platonic Solids to Anti-RetroViral ActiVity; Kluwer Academic Publishers: Dordrecht, The Netherlands, 1994 @No $ @ @ (a) Heravi M. M. Bakhtiari K. H. and Bamoharram F. F., An efficient and chemoselective synthesis of acylals from aromatic aldehydes and their regeneration, catalyzed by 12-molybdophosphoric acid, Catal. Commun., , 499-501 2006) (b) Heravi M. M. Bamoharram F. F. Rajabzadeh G. Seifi N. and Khatami M., Preyssler heteropolyacid [NaP3011014, as a new, green and recyclable catalyst for the synthesis of [1,2,4]triazino[4,3-b][1,2,4,5]tetrazines, J. Mol. Catal. A: Chem., 259, 213-217 (2006) @No $ @ @ Heravi M. M. Bakhtiari K. and Bamoharram F. F., 12-Molybdophosphoric acid: A recyclable catalyst for the synthesis of Biginelli-type 3,4-dihydropyrimidine-2(1H)-ones, Catal.Commun., , 373-376 (2006) @No 
<#LINE#>Environmental Geochemistry of Core Sediment in the Cochin Estuary (CE), India<#LINE#>ManjuP.@Nair,Sujatha@C.H.<#LINE#>65-69<#LINE#>10.ISCA-RJCS-2013-037.pdf<#LINE#>Department of Chemical Oceanography, School of Marine Sciences, Cochin University of Science and Technology, Kochi-16, Kerala, INDIA<#LINE#>6/3/2013<#LINE#>14/3/2013<#LINE#> Distribution of toxic metal in the sediment core is an important area of research for environmental impact studies. Sediment cores were collected from two prominent region(C and C)  of CE and subjected to geochemical analysis to determine distribution of toxic metals (Cd, Co, Cr, Cu and Pb ), texture characteristics, total organic carbon (TOC) and CHNS. Statistical analysis was done to understand the interrelationship between the components. In the studied cores, metal contamination level was identified for Pb, Cu; Cr, in C and C respectively. The metal distribution depends on the granulometric factor, geogenic mineral components and anthropogenic input. Correlation analysis (CA) and Principal component(PCA) analysis also support these results.<#LINE#> @ @ Clement R.E., Eiceman G.A., Koester C.J., Environmental analysis, Anal Chem, 67(12), 221R–225R (1995) @No $ @ @ MacCarthy P., Klusman R.W., Cowling SW et al., Water analysis, Anal Chem, 63(12), 301–342 (1991) @No $ @ @ Mohan D., Singh K.P., Single-and multi-component adsorption of cadmium and zinc using activated carbon derived from bagasse—an agricultural waste, Water Res, 36(9), 2304–2318 (2002) @No $ @ @ Mohan D., Pittman J.C.U. and Steele P.H., Single, binary and multicomponent adsorption of copper and cadmium from aqueous solutions on Kraft lignin—a biosorbent, J Colloid Interf Sci.,297(2), 489–504 (2006) @No $ @ @ Dali-youcef N., Ouddane B. and Derriche Z., Adsorption of zinc on natural sediment of Tafna River (Algeria), J Hazard Mater, 137(3), 1263–1270 (2006) @No $ @ @ Mohan D., Pittman J.C.U. and Bricka M. et al, Sorption of arsenic, cadmium, and lead by chars produced from fast pyrolysis of wood and bark during bio-oil production, J Colloid Interf Sci, 310(1), 57–73 (2007) @No $ @ @ Manju P. Nair and Sujatha C.H., Biogeochemical quality assessment of the sediments in Kerala coast,International Journal of Environmental Sciences, 3(1), 707-719 ( 2012) @No $ @ @ Manju P. Nair, Akhil P.S. and Sujatha C.H., Geochemistry of Core Sediment from Antarctic Region, Research journal of chemistry and environment, 17(2), 8-12(2013) @No $ @ @ Cohen A.S., Paliolimnology, Oxford University Press, New York (2003) @No $ @ @ Alemdaroglu T., Onur E., Erkakan F., Trace metal levels in surface sediments of lake Manyas, Turkey and tributary rivers, Int. J. Environ. Stud, 60(3), 287-298 (2003) @No $ @ @ Unnikrishnan P. and Nair S.M., Partitioning of trace metals between dissolved and particulate phases in a typical backwater system of Kerala, India, Int. J. Environ. Studies, 61(6), 659-676 (2004) @No $ @ @ Balachandran K.K., Joseph T., Nair M., Sankaranarayanan V.N., Das V.K. and Sheeba P., Geochemistry of surficial sediments along the central southwest coast of India-seasonal changes in regional distribution, J. Coast. Res.,19(3), 664- 683 (2003) @No $ @ @ Balachandran K.K., Laluraj C.M., Nair M., Joseph T., Sheeba P. and Venugopal P., Heavy metal accumu-lation in a flow restricted, tropical estuary, Estuarine, Coastal and Shelf Science, 65, 361–370 (2005) @No $ @ @ Balachandran K.K., Laluraj C.M., Martin G.D., Srinivas K. and Venugopal P., Environmental analysis of heavy metal deposition in a flow-restricted tropical estuary and its adjacent shelf, Environmental Forensics, , 345–351 (2006) @No $ @ @ Harikumar P.S., Nasiru P. and Mujeeburahmanm P., Distribution of heavy metals in the core sediments of a tropical wetland system, International journal of environmental science and technology, 6(2), 225–232 (2009) @No $ @ @ Renjith K.R. and Chandramohanakumar N., Distribution of heavy metals in the surficial sediments of a complex micro-tidal estuarine system in southwest India, Research journal of chemistry and environment,13(2), 34–44 (2009) @No $ @ @ Ratheesh Kumar C.S., Joseph M.M., Gireesh Kumar T.R., Renjith K.R., Manju M.N. and Chandramohanakumar N., Spatial variability and contamination of heavy Metals in the inter-tidal systems of a tropical environment, International journal of environmental research,4(4), 691–700 (2010) @No $ @ @ Paneer Selvam A.,  Laxmi Priya S.,  Kakolee Banerjee G. Hariharan,   R. Purvaja,  R. Ramesh, Heavy metal assessment using geochemical and statistical tools in the surface sediments of vembanad lake, southwest coast of India,  Environmental  Monitoring  Assessment,184, 5899–5915 (2012) @No $ @ @ Lewis D.W., Practical Sedimentology, Huchinson Ross Publishing Co; Stroudsburg. Pa 22 (1984) @No $ @ @ Loring D.H. and Rantala R.T.T., Manual for the geochemical analyses of marine sediments and suspended matter, Earth-science reviews,32, 235-283 (1992) @No $ @ @ Perdue, E.M., and Koprivnjak J.F., Using the C/N ratio to estimate terrigenous inputs of organic matter to aquatic environments, Estuarine, Coastal and Shelf Science,73, 65-72 (2007) @No $ @ @ Berner R. and Raiswell R., C/S method for distinguishing fresh water from marine sedimentary rocks, Geology12,365-368 (1983 ) @No $ @ @ Balachandran K.K., Reddy G.S., Revichandran C., Srinivas K., Vijayan P.R. and Thottam T.J., Modelling of tidal hydrodynamics for a tropical ecosystem with implications for pollutant dispersion (Cohin Estuary, Southwest India), OceanDynamics, 58(3-4), 259–273 (2008) @No $ @ @ Birth G., A scheme for assessing human impacts on coastal aquatic environments using sediments, (In: Woodcofie C.D., Furness R.A. (Eds.) Coastal GIS 2003.Wollongong University Papers in Center for Maritime Policy, 14, Australia (2003) @No 
<#LINE#>Assessment of Nutrients and Stability Parameters during Composting of Water Hyacinth mixed with Cattle Manure and Sawdust<#LINE#>Ravi@Prasad,Jiwan@Singh,AjayS.@Kalamdhad<#LINE#>70-77<#LINE#>11.ISCA-RJCS-2013-039.pdf<#LINE#> Department of Civil Engineering, Indian Institute of Technology Guwahati (IITG), Guwahati-781039 Assam, INDIA<#LINE#>7/3/2013<#LINE#>13/3/2013<#LINE#> Water hyacinth (Eichhornia crassipes) can cause a variety of problems due to its fast spread and congested growth. Nutrient recycling through the composting of water hyacinth can reduce application of chemical fertilizers to the agricultural field and problems related to its fast growth rate. The nutrients and stability parameters were evaluated during agitated pile composting of water hyacinth mixed with cattle manure and sawdust for 30 days composting period. Five different proportions of cattle manure, water hyacinth and sawdust were prepared for the composting process. Stability of compost was evaluated using respiration techniques (CO evolution and oxygen uptake rate). Results show that nutrients (Na, K, Ca, Mg, total nitrogen, phosphorus) were increased significantly during the composting process. Stability parameters (COevolution rate and oxygen uptake rate, biochemical chemical oxygen demand and chemical oxygen demand) were reduced during the process. The optimum proportion of cattle manure enhanced organic matter degradation and humification during the composting process.  <#LINE#> @ @ Rai P.K., Heavy metal phytoremediation from aquatic ecosystems with special reference to macrophytes, Crit. Rev. Env. Sci. Technol., 39, 697–753 (2009) @No $ @ @ Gunnarsson C.C. and Petersen C.M., Water hyacinths as a resource in agriculture and energy production, A literature review, Waste Manage.,  27, 117-129 (2007) @No $ @ @ Haug R.T. The practical handbook of composting engineering Lewis publishers Boca Raton (1993) @No $ @ @ Huang G.F., Wong J.W.C. We Q.T. and Nagar B.B., Effect of C/N on composting of pig manure with sawdust, Waste manage.,24, 805-813 (2004) @No $ @ @ Parkinson R. Gibbs P. Burchett S. and Misselbrook T., Effect of turning regime and seasonal whether conditions on nitrogen and phosphorus losses during aerobic composting of cattle manure, Bioresour. Technol., 91, 171-178 (2004) @No $ @ @ Jouraiphy A. Amir S. El Gharous M. Revel J.C. and Hafidi M.,Chemical and spectroscopic analysis of organic matter transformation during composting of sewage sludge and green plant waste, Int. Biodeterior. Biodegrad., 56, 101-108(2005) @No $ @ @ Kalamdhad A.S., Singh Y.K. and Ali M., Khwairakpam and Kazmi A.A. Rotary drum composting of vegetable waste and tree leaves, Bioresour. Technol., 100, 6442–6450 (2009) @No $ @ @ Zucconi F., Monaco A., Forte M de and Bertoldi M., Phytotoxins during the stabilization of organic matter. In Grasser JKR editor. Composting of agricultural and other wastes, Amsterdam, Elsevier Science B.V, 73–86 (1985) @No $ @ @ Lasaridi K.E. and Stentiford E.I., A simple respirometric technique for assessing compost stability. Water Res.,32, 3717–3723 (1998) @No $ @ @ Gomez R.B., Lima F.V. and Ferrer AS., The use of respiration indices in the composting process, a review, Waste Manage.t Res., 24, 37–47 (2006) @No $ @ @ Tiquia S.M. and Tam N.F.Y., Fate of nitrogen during composting of chicken litter, Environ. Pollut., 110, 535-541 (2000) @No $ @ @ APHA Standard methods for the examination of water and wastewater. 21st edition, American Public Health Association, Washington DC (2005) @No $ @ @ Kalamdhad A.S., Pasha M. and Kazmi A.A. Stability evaluation of compost by respiration techniques in a rotary drum composter. Resour. Conserv. Recy.,52, 829–834 (2008) @No $ @ @ Chen Y.X., Huang X.D., Han Z.Y., Huang X., Hu B., Shi D.Z. and Wu W.X., Effects of bamboo charcoal and bamboo vinegar on nitrogen conservation and heavy metals immobility during pig manure composting, Chemosphere, 78, 1177-1181 (2010) @No $ @ @ Amir S., Hafidi M., Merlina G. and Revel J.C., Sequential extraction of heavy metals during composting of sewage sludge, Chemosphere, 59, 801–810 (2005) @No $ @ @ Fang M. and Wong J.W.C., Effects of lime amendment on availability of heavy metals and maturation in sewage sludge composting, Environ. Pollut., 106, 83-89 (1999) @No $ @ @ Zaranyika M.F., Mutoko F. and Murahwa H., Uptake of Zn, Co, Fe and Cr by water hyacinth (Eichhornia crassipes) in Lake Chivero, Zimbabwe, Sci. Total Environ., 153, 117-121(1994) @No $ @ @ Zorpas A.A., Constantinides T. and Vlyssides A.G., Haralambous I. and Loizidou M., 2000. Heavy metal uptake by natural zeolite and metals partitioning in sewage sludge compost. Bioresour. Technol., 72, 113-119 (2000) @No $ @ @ Singh Y.K., Kalamdhad A.S., Ali M. and Kazmi A.A., Maturation of primary stabilized compost from rotary drum composter, Resour. Conserv. Recy.,53, 386–392 (2009) @No $ @ @ Hue N.V. and Liu J., Predicting compost stability, Compost Sci.Util.,3 (2) 8–15 (1995) @No $ @ @ Hassen A., Belguith K., Jedidi N., Cherif A., Cherif M. and Boudabous A., Microbial characterization during composting of municipal solid waste, Bioresour. Technol., 80, 217- 225 (2001) @No
@Short Communication
<#LINE#>A Facile Route for the Preparation of Phosphonic Acid Grafted Nanosized Hydroxyapatite Biomaterial<#LINE#>Nabakumar@Pramanik,Sudip@Chakraborty<#LINE#>78-80<#LINE#>12.ISCA-RJCS-2013-006.pdf<#LINE#>Department of Chemistry, National Institute of Technology, Arunachal Pradesh, INDIA @ Department of Chemistry, Indian Institute of Technology, Kharagpur-721302, INDIA<#LINE#>6/1/2013<#LINE#>23/1/2013<#LINE#> The present research effort consists in the development of phosphonic acid grafted nanosized hydroxyapatite (n-HAp) through a straightforward chemical methodology. Fourier transform infrared absorption spectroscopy (FTIR) and electron diffraction X-ray (EDX) studies show the stoichiometric creation of HAp particles. The existence of phosphonic acid on the hydroxyapatite particle surface was investigated through FTIR study also. Transmission electron microscopy (TEM) analysis divulges needle like acicular crystals of HAp particles with inexact size of 25-33 nm in diameter by 70-85 nm in length. The prepared hydroxyapatite material may be used in building a biocomposite with high interfacial bonding.<#LINE#> @ @ Hench L.L., Bioceramics, J. Am. Ceram. Soc.,81, 1705 (1998) @No $ @ @ Bacon G.E., Bacon P.J. and Griffiths R.K., Neutron diffraction studies of lumbar vertebrae, J. Anat.,128, 277 (1979) @No $ @ @ Sinha A., Nayar S., Agrawal A., Bhattacharyya D. and Ramachandrarao P., Synthesis of nanosized and Microporous precipitated Hydroxyappatite in synthetic polymers and Biopolymers, J. Am. Ceram. Soc., 86, 357 (2003) @No $ @ @ Mishra D.N., Adsorption of Low-molecular-weight Sodium Polyacrylate on Hydroxyapatite, J. Dent. Res.,64, 1405 (1985) @No $ @ @ Liu Q., De Wijn J.R., Bakker D., Van Toledo M. and Van Blitterswijk C.A., An introduction to materials and medicine, J. Mater. Sci.: Mater. Med., , 23 (1998) @No $ @ @ Liu Q., De Wijn J.R. and Van Blitterswijk C.A., A study on the grafting reaction of isocyanates with hydroxyapatite particles, J. Biomed. Mater. Res.,40, 358 (1998) @No $ @ @ Abboud M., Turner M., Duguet E. and Fontanille M., PMMA based composite materials with reactive ceramic fillers. Part 1–Chemical modification and characterisation of ceramic particles, J. Mater. Chem.,7, 1527 (1997) @No $ @ @ Greish Y.E. and Brown P.W., Preparation and characterization of calcium phosphate-poly(vinyl phosphonic acid) composites, J. Mater. Sci.: Mater. Med.,12, 407 (2001) @No $ @ @ Mou L., Singh G. and Nicholson J.W., Synthesis of a hydrophilic phosphonic acid monomer for dental materials, Chem. Commun.,5, 345 (2000) @No $ @ @ Landi E., Tampieri A., Celotti G. and Sprio S., Densification Behavior and Mechanisms of Synthetic Hydroxyapatites, J. Eur. Ceram. Soc.,20, 2377 (2000) @No $ @ @ Dorozhkin S.V. and Epple M., Biological and Medical Significance of Calcium Phosphates, Angew. Chem.,41,3130 (2002) @No $ @ @ Pramanik N., Bhargava P., Alam S. and Pramanik P.,Processing and Properties of Nano- and Macro- Hydroxyapatite/ Poly(ethylene-co-acrylic acid) Composite, Polym. Compos.,27, 633 (2006) @No
<#LINE#>QSAR Study of Rabbit Aortic Angiotensin II Antagonists Compounds ising Different Descriptors<#LINE#>B.N.@Singh,Kalpana@Singh,Kaleem@Ahmad<#LINE#>81-83<#LINE#>13.ISCA-RJCS-2013-019.pdf<#LINE#> 1Department of Chemistry, Kisan PG College Bahraich, UP, INDIA @ Department of Chemistry, Mahila PG College Bahraich, UP, INDIA  <#LINE#>6/2/2013<#LINE#>13/2/2013<#LINE#>  For present study, the various QSAR models have been developed to predict the activities in terms of log 1/C for 11 Rabbit Aorta Angiotensin II Antagonists compounds with the help of quantum chemical and energy descriptors viz. heat of formation, Gibbs  free energy, molar refractivity, HOMO energy, LUMO energy, absolute hardness, Softness, Chemical potential and electronegativity. The parameter adopted in this calculation is the semi-empirical PM3 based. The QSAR model sixth provides a good arrangement between obs log 1/c and predicted activity.    <#LINE#> @ @  Hansch C., Maloney P.P., Fujita T. and Muir R.M., Nature, 194, 178 (1962) @No $ @ @  Hansch C., Acc. Chem. Res., 26, 147 (1993) @No $ @ @  Hansch C., Hoekman D. and Gao H., Chem. Rev., 96, 1045 (1996) @No $ @ @  Gao H. and Hansch C., Drug Metab. Rev., 18, 513 (1996) @No $ @ @  Hansch C. and Gao H., Chem. Rev., 97, 2995 (1997) @No $ @ @  Hansch C., Gao H. and Hoekman D., Comparative QSAR; Devillers J., Ed.; Taylor and Francis: London, 285, (1998) @No $ @ @  Gao H., Katzenellenbogen J.A., Garg R., Hansch C., Chem.Rev., 99, 723 (1999) @No $ @ @  Selassie C.D., Shusterman A.J., Kapur S., Verma R.P., Zhang L., Hansch C., J. Chem. Soc., Perkin Trans., 2, 2729 (1999) @No $ @ @  Garg R., Gupta S.P., Gao H., Babu M.S., Debnath A.K. and Hansch C., Chem. Rev., 99, 3525 (1999) @No $ @ @  Hansch C., Kurup A., Garg R. and Gao H., Chem. Rev., 101, 619 (2001) @No $ @ @  Hansch C., J. Chem. Educ., 51, 360 (1974) @No $ @ @  Peach M.J., Physiol. Rev., 57, 313 (1977) @No $ @ @  Dzau V.J. and Pratt R.E., Handbook of Experimental Cardiology, Haber E., Morgan H., Katz A., Fozard H., Eds., Raven: New York, D1631 (1986) @No $ @ @  Ondetti M.A. and Cushman D.W., J. Med. Chem., 24, 355 (1981) @No $ @ @  Mulliken R.S., J. Chem. Phys., 2, 782 (1934) @No $ @ @  Parr R.G. and Pearson R.G., J. Am. Chem. Soc., 105, 7512 (1983) @No $ @ @  Pearson R.G., J. Am. Chem. Soc., 85, 3533-3539 (1963) @No $ @ @  Parr R.G. and Pearson R.G., Journal of the American Chemical Society, 105(26), 7512 e7516 (1983) @No $ @ @  Iczkowski R. and Margrave J.L., Journal of the American Chemical Society, 83(17), 3547 (1961) @No
<#LINE#>Spectroscopic study of Inner Transition metal Mn2  ion in CeSO4Cl Phosphor<#LINE#>Gedam@S.C.<#LINE#>84-86<#LINE#>14.ISCA-RJCS-2013-025.pdf<#LINE#> K.Z.S. Science College Kalmeshwar, Nagpur 441501, INDIA<#LINE#>18/2/2013<#LINE#>25/2/2013<#LINE#> CeSOCl: Mn phosphor is prepared by wet chemical method. The spectroscopic study and electronic states of Mn2+ are derived from excitation spectra for greenemitting CeSOCl: Mn phosphor and is found to give a spectrum consistent with linear symmetry in increasing intensity of Mn2+ ion. Mn2+ emission at 535 nm was observed in the present host due to  transition. The emission spectra shows single peak having sharp shape and strong intensity at 535 nm. It can be used as a green phosphor.  <#LINE#> @ @ Blasse G. and Grabmaier B.C., Luminescent Materials. Springer-Verlag, Berlin, 232, (1994) @No $ @ @ Koskentalo T., Leskela M. and Niinisto L., Mater.Res.Bull., 20, 265-271 (1985) @No $ @ @ Wyckoff R.W.G., Crystal Structures, 2(2), edn.Wiley, New York (1964) @No $ @ @ Lammers M.J.J, and Blasse G., Nanotechnology Applications for Clean Water, Phys.Status Solidi (b), 127,663-669 (1985) @No $ @ @ Sunta C., A review of thermoluminescence of calcium fluoride, calcium sulphate and calcium carbonate, Radiat. Prot. Dosim.,, 25-32 (1984) @No $ @ @ McKeever S.W.S., Moscovitch M. and Townsend P.D., Thermoluminescence Dosimetry Materials: Properties and Uses(Ashford: Nuclear Technology) (1995) @No $ @ @ Chaoshu Shi, Zhijian Xie, Deng Jie, Dong Yi, Xiaoyu Yang, Yiguan Hu, Yangchao Tian, Kan Ya and Chen Gun, Thermoluminescence of BaF2: RE (Ce, Eu, Eu) crystals, J. Electron Spectrosc. Relat. Phenom.,79, 87-92       (1996) @No $ @ @ Becker J., Zimmerer G. and Shi C., Anion- and cation-type energy transfer in BaF2: Eu, J. Lumin., 72, 906-911 (1997) @No $ @ @ Salis M., Investigating crystal defects in BaF2 and SrF2 by thermoluminescence experiments Nuovo Cimento D 19, 95-100 (1997) @No $ @ @ Drozdowski W., Przegietka K., Wojtowicz A. and Oczkowski, H. Charge traps in Ce-doped CaF2 and BaF2, Acta Phys. PolA 95, 251-256 (1999) @No $ @ @ Lucas A. and Kapsar B., The thermoluminescence of BaF2:Eu Proc. 4th Int. Conf. on Luminescence Dosimetry (Krakow),, 507-512 (1974) @No $ @ @ Blasse G., Bril A., The absorption and emission spectra of some important activators, Phillips Tech. Rev., 31,  304 (1970) @No $ @ @ Palumbo D.T., Brown J.J., Jr., Electronic States of Mn2+Activated Phosphors, J. Electrochem. Soc., 117, 1184 (1970) @No 
@Review Paper
<#LINE#>Corrosion inhibition study of Stainless steel in Acidic medium– An Overview<#LINE#>P.@Selvakumar,Karthik@B.Balanaga,C.@Thangavelu<#LINE#>87-95<#LINE#>15.ISCA-RJCS-2013-034.pdf<#LINE#>Department of chemistry, Chettinad college of Engineering and Technology, Karur- 639114, Tamilnadu, INDIA @ Department of Chemistry, Periyar EVR College (Autonomous), Tiruchirapalli – 620023, Tamilnadu, INDIA <#LINE#>4/3/2013<#LINE#>22/3/2013<#LINE#> Inhibition of corrosion with different types of stainless steel, medium and inhibitors has been reviewed. Corrosion can be controlled or minimized by the use of inhibitors. Acids are frequently used to remove such scales including hydrochloric acid (HCl), sulphuric acid (HSO), sulfamic acid (HNSO) and phosphoric acid (HPO). There is a continuous search for better corrosion inhibitors to meet the need of the industrial expectations. The inhibition’s efficiency of inhibitor compounds is strongly dependent on the structure and the chemical properties of the film formed on the metal surface. The adsorption of inhibitors on the metal surface through polar atoms will prevent corrosion. The protection of metals from corrosion is analyzed by many technologies such as weight loss, Open Circuit Potential (OCP), Potentiodynamic Polarization, Electrochemical Impedance Spectra (EIS), X-ray Photoelectron Spectroscopy (XPS), X-ray Diffraction spectroscopy (XRD), Energy Dispersive X-ray Spectroscopy (EDX), Scanning Electron Microscope (SEM), FTIR, UV-Visible spectra and adsorption study. <#LINE#> @ @ Bockris J.O.M. and Reddy A.K.N., Modern Electrochemistry 2B, Electrodics in chemistry, Engineering, biology and Environmental Science, second ed., Kluwer Academic plenum publishers, New York, 1703 2000) @No $ @ @ Ashassi–Sorkhabi H.,  Asghari, Effect of hydrodynamic conditions on the inhibition performance of L-methionine as a green inhibitor, J. Electrochim Acta., 54, 162-167 2008 @No $ @ @ Reeta Agarwal and Namboodhiri T.K.G., The inhibition of sulphuric acid corrosion of 410 stainless steel by thioureas, J.Corros. Sci, 30, 37-52 (1990) @No $ @ @ Urgen M. and Cakir A.F., The Effect of Molybdate ions on the temperature dependent pitting potential of austenitic Stainless steel in neutral chloride solutions, J. Corros. Sci., 32, 841-852 (1991). @No $ @ @ Lu. Y.C. and Ives M.B., The improvement of the localized corrosion resistance of Stainless steel by cerium, J. Corros. Sci., 34, 1773-1785 (1993) @No $ @ @ Zhou Mingpeng, Wang Kaiming, DiaoYuemin and Zhou Bensheng, Corrosion inhibition of methylenephosphonic acids with R-N-[CHPO(OH) structure in sulpuric acid solution, J. Chinese Society of Corrosion and Protection., 14,  283-290 (1994) @No $ @ @ Al-Mayout A.M, Al-Suhybani A.A., Al-Ameery A.K., Corrosion inhibition of 304SS in sulphuric acid solutions by 2-methyl benzoazole derivatives, Desalination, 116,  25-33 (1998). @No $ @ @ Yang W.Z. and Zhou B.S., Study on corrosion inhibition by N-Sulfonic aminodimethylenephosphonicacid, J. Chinese Society of Corrosion and Protection, 20, 105-110 (2000) @No $ @ @ Gopi D. and Rajeswari S., Surface characterization and electrochemical corrosion behavior of 304stainless steel in aqueous media, J. Solid State Electrochemistry,, 194-202 (2002) @No $ @ @ Abdallah M., Rhodanine azosulpha drugs as corrosion inhibitors for corrosion of 304stainless steel in hydrochloric acid solution, J. Corros. Sci., 44, 717-728 (2002) @No $ @ @ Paul A. Kilmartin, Lissa Trier, Graham, A, Wright, Corrosion inhibition of polyaniline and poly (o-methoxyaniline) on stainless steels, Synthetic metals, 131,  99-109 (2002) @No $ @ @ Denise S., Azambuja Emilse M.A., Martini and Iduvirges L. Muller, Corrosion behavior of Iron and AISI 304 stainless steel in Tungstate Aqueous solutions containing chloride, J. Braz.Chem.Soc., 14,  570-576 (2003) @No $ @ @ Abdallah M., Corrosion behavior of 304stainless steel in sulphuric acid solutions and its inhibition by some substituted pyrazolones, Materials Chemistry and Physics, 82, 786–792 (2003) @No $ @ @ Refaey S.A.M., Taha F., Abd El-Malak A.M., Inhibition of stainless steel pitting corrosion in acidic medium by 2-mercaptobenzoxazole, Applied Surface Sci., 236, 175–185 (2004) @No $ @ @ Celeste Rabacal Alentejano, Idalina Vieira Aoki, Localized corrosion inhibition of 304stainless steel in pure water by oxyanions tungstate and molybdate, Electrochemica Acta., 49, 2779-2785 (2004) @No $ @ @ Meltem Dudukcu, Birgul Yazici, Mehmet Erbil, The effect of indole on the corrosion behaviour of stainless steel, Materials Chemand Phy., 87, 138–141 (2004) @No $ @ @ Behpour M., Ghoreishi. S.M., Mohammadi N., SalavatiNiasari.MN-[(Z)-1-Phenylemethyleidene]-N-{2-[(2-{[(Z)-1 phenylmethylidine]amino}phenyl)disulfanyl] phenyl} amine and its derivatives on the corrosion of stainless steel 304 in acid media, J. Corros. Sci., 53,  3380-3387 (2005) @No $ @ @ Galal A., Atta N.F., Al-Hassan M.H.S., Effect of some thiophene derivative on the electrochemical behaviour of AISI 316austenitic stainless steel in acidic solutions containing chloride ions, I. Molecular structure and inhibition efficiency relationship, Materials Chem and Phy., 89,  38-48 (2005) @No $ @ @ Narvaez L., Cano E. and Bastidas D.M., 3-Hydroxybenzoic acid as AISI 316Lstainless steel corrosion inhibitor in a SO-HF-H pickling solution, J.Applied Electrochemistry, 35,  499-506 (2005) @No $ @ @ . Galal A., Atta N.F., Al-Hassan M.H.S., Effect of some thiophene derivatives on the electrochemical behavior of AISI 316austenitic stainless steel in acidic solutions containing chloride ions II, Effect of temperature and surface studies, Materials Chem and Phy., 89, 28–37 (2005) @No $ @ @ Sourisseau T., Chauveaub E. and Barouxa B., Mechanism of copper action on pitting phenomena observed on stainless steels in chloride media, J. Corros. Sci., 47, 1097– 1117 (2005) @No $ @ @ Refaey S.A.M., Taha F., Abd El-Malak A.M., Corrosion and inhibition of 316Lstainless steel in neutral medium by 2 Mercaptobenzimidazole, Int. J.Electrochem. Sci., 1, 80- 91 (2006) @No $ @ @ Silva A.B., Agostinho S.M.L., Barcia O.E., CordeiroG.G.O. and E. D’Elia, The effect of cysteine on the corrosion of 304L stainless steel in sulphuric acid, J. Corros. 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