Characterization of Ruthenium Based Metal Complex Nanoparticles Decorated on Carbon Supported Surface

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Characterization of Ruthenium Based Metal Complex Nanoparticles Decorated on Carbon Supported Surface

Author Affiliations

¹Department of Chemistry, Indian Institute of Technology, Kharagpur-721302, INDIA
²Department of Chemistry, National Institute of Technology, Arunachal Pradesh, INDIA

Res.J.chem.sci., Volume 3, Issue (2), Pages 31-34, February,18 (2013)

Abstract

The ruthenium oxide-hexacyanoferrate nanoparticles (RuOHCFNP) were prepared by an electroless deposition approach and the electrochemical, spectral and morphological behavior of RuOHCFNP modified electrode has been investigated. RuOHCFNP were well decorated on the walls of carbon nanotubes and shows stable voltammetric response. This electrode is highly stable with high reproducibility.

References

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Wong E.W., Sheehan P.E. and Lieber C.M., Nanobeam Mechanics: Elasticity, Strength and Toughness of Nanorods and Nanotubes, Science, 277, 1971 (1997)
Wang J., Carbon-Nanotube Based Electrochemical Biosensors: A Review, Electroanalysis, 17, 7 (2005)
Gong K., Dong Y., Xiong S., Chen Y. and Mao L., Novel electrochemical method for sensitive determination of homocysteine with carbon nanotube-based electrodes, Biosens. Bioelectron., 20, 253 (2004)
Cox J.A. and Kulesza P.J., Electrocatalytic oxidation and determination of arsenic(III) on a glassy carbon electrode modified with a thin film of mixed-valent ruthenium(III, II) cyanide, Anal. Chem., 56, 1021 (1984)
Itaya K., Ataka T. and Toshima S., Spectroelectrochemistry and electrochemical preparation method of Prussian blue modified electrodes, J. Am. Chem. Soc., 104, 4767 (1982)
Zhou D.M., Ju H.X. and Chen H.Y., Catalytic oxidation of dopamine at a microdisk platinum electrode modified by electrodeposition of nickel hexacyanoferrate and Nafion, J. Electroanal. Chem., 408, 219 (1996)
Chakraborty S. and Pramanik N., Electroless Deposition of Metal Hexacyanoferrate on Carbon nanotube Supported Electrode for Electrocatalytic Sensing of Ethanol, Int. J. Eng. Res. Application., 2, 1015 (2012)
Chen S.M. and Hsueh S.H., Preparation, characterization and electrocatalytic properties of polynuclear mixed-valent ruthenium oxide/hexacyanoruthenate film modified electrodes, J. Electroanal. Chem., 566, 291 (2004)
K. Kasem, F.R. Steldt, T.J. Miller, A.N. Zimmerman, Electrochemical synthesis of zeolite-like ruthenium-based hexacyanometalates multi-film assemblies, Microp. Mesop. Mater., 66, 133 (2003)
Chen S.M., Lu M. and Lin K., Preparation and characterization of ruthenium oxide/hexacyanoferrate and ruthenium hexacyanoferrate mixed films and their electrocatalytic properties, J. Electroanal. Chem.., 579, 163 (2005)
N. R. de Tacconi and K. Rajeshwar, Metal Hexacyanoferrates: Electrosynthesis, in Situ Characterization, and Applications, Chem. Mater., 15, 3046 (2003)
Yang M., Jiang J., Yang Y., Chen X., Shen G. and Yu R., Carbon nanotube/cobalt hexacyanoferrate nanoparticle-biopolymer system for the fabrication of biosensors, Biosens. Bioelectron, 21, 1791 (2006)

[ref1] Iijima S., Helical microtubules of graphitic carbon, Nature, 354, 56 (1991)

[ref2] Wong E.W., Sheehan P.E. and Lieber C.M., Nanobeam Mechanics: Elasticity, Strength and Toughness of Nanorods and Nanotubes, Science, 277, 1971 (1997)

[ref3] Wang J., Carbon-Nanotube Based Electrochemical Biosensors: A Review, Electroanalysis, 17, 7 (2005)

[ref4] Gong K., Dong Y., Xiong S., Chen Y. and Mao L., Novel electrochemical method for sensitive determination of homocysteine with carbon nanotube-based electrodes, Biosens. Bioelectron., 20, 253 (2004)

[ref5] Cox J.A. and Kulesza P.J., Electrocatalytic oxidation and determination of arsenic(III) on a glassy carbon electrode modified with a thin film of mixed-valent ruthenium(III, II) cyanide, Anal. Chem., 56, 1021 (1984)

[ref6] Itaya K., Ataka T. and Toshima S., Spectroelectrochemistry and electrochemical preparation method of Prussian blue modified electrodes, J. Am. Chem. Soc., 104, 4767 (1982)

[ref7] Zhou D.M., Ju H.X. and Chen H.Y., Catalytic oxidation of dopamine at a microdisk platinum electrode modified by electrodeposition of nickel hexacyanoferrate and Nafion, J. Electroanal. Chem., 408, 219 (1996)

[ref8] Chakraborty S. and Pramanik N., Electroless Deposition of Metal Hexacyanoferrate on Carbon nanotube Supported Electrode for Electrocatalytic Sensing of Ethanol, Int. J. Eng. Res. Application., 2, 1015 (2012)

[ref9] Chen S.M. and Hsueh S.H., Preparation, characterization and electrocatalytic properties of polynuclear mixed-valent ruthenium oxide/hexacyanoruthenate film modified electrodes, J. Electroanal. Chem., 566, 291 (2004)

[ref10] K. Kasem, F.R. Steldt, T.J. Miller, A.N. Zimmerman, Electrochemical synthesis of zeolite-like ruthenium-based hexacyanometalates multi-film assemblies, Microp. Mesop. Mater., 66, 133 (2003)

[ref11] Chen S.M., Lu M. and Lin K., Preparation and characterization of ruthenium oxide/hexacyanoferrate and ruthenium hexacyanoferrate mixed films and their electrocatalytic properties, J. Electroanal. Chem.., 579, 163 (2005)

[ref12] N. R. de Tacconi and K. Rajeshwar, Metal Hexacyanoferrates: Electrosynthesis, in Situ Characterization, and Applications, Chem. Mater., 15, 3046 (2003)

[ref13] Yang M., Jiang J., Yang Y., Chen X., Shen G. and Yu R., Carbon nanotube/cobalt hexacyanoferrate nanoparticle-biopolymer system for the fabrication of biosensors, Biosens. Bioelectron, 21, 1791 (2006)