9th International Science Congress (ISC-2019).  International E-publication: Publish Projects, Dissertation, Theses, Books, Souvenir, Conference Proceeding with ISBN.  International E-Bulletin: Information/News regarding: Academics and Research

Ultrasonic study of molecular interactions in binary mixtures of isopropylbenzene (Cumene) with Benzene, Toluene and Acetone at 303K

Author Affiliations

  • 1Department of Physics, N.M.S.N. Dass College-Budaun-243601 UP,INDIA

Res.J.chem.sci., Volume 3, Issue (2), Pages 27-30, February,18 (2013)


The ultrasonic velocity, density and viscosity at 303K have been measured in the binary systems of isopropylbenzene+Benzene, isopropylbenzene + Toluene and isopropyl benzene + Acetone. From the experimental data various acoustical parameters such as adiabatic compressibility (&bita;), free volume(Vƒ), Shear relaxation time(ζ), free length(Lƒ) and acoustical impedance (Z) ere calculate. The results are interpreted in terms of molecular interaction between the components of the mixtures.


  1. Sharma C.K. and Kanwar S.S., Synthesis of methyl cinnamate using immobilized lipase from B. licheniformis MTCC-10498 , Res.J.Recent Sci., 1(3), 68-71 (2012)
  2. Pascal C., Agbangnan D., Christine Tachon, Justine Dangou, Anna Chrostowska, Eric Fouquet and Dominique C.K. Sohounhloue, Optimization of the Extraction of Sorghum's Polyphenols for Industrial Production by Membrane Processes, Res.J.Recent Sci., 1(4), 1-8 (2012)
  3. Mudigoudra B.S., Masti S.P., Chougale R.B., Thermal Behavior of Poly (vinyl alcohol)/ Poly (vinyl pyrrolidone)/Chitosan Ternary Polymer Blend Films, Res.J.Recent Sci., 1(9), 83-86 (2012)
  4. Anbarasu S. and Devarajan Prem Anand, Uniaxial Growth and Characterization studies of [(para methoxy phenyl) imino] benzene NLO crystal by Sankaranarayanan- Ramasamy Method, Res. J. Recent Sci., 1(10), 37-44 (2012)
  5. Mahdi Safaa A., Muhsin Asaad H. and Al-Mosawi Ali I., Using Ultrasonic Sensor for Blind and Deaf persons Combines Voice Alert and Vibration Properties, Res. J. Recent Sci., 1(11),50-52, 2012)
  6. Redlich O. and Kister A.T., Algebraic Representation of Thermodynamic properties and the classification of Solution, Ind Eng Chem., 40, 345 (1948)
  7. Jacobson B, Association number in liquid systems from intermolecular free length relationship, Acta Chim Scand,, 1485 (1952)
  8. Ali A., Nain A.K. and Kamil M., Physico-chemical studies of non aqueous binary liquid mixtures at various temperatures, Thermochim Acta,274 , 209 (1996)
  9. Ali A., Hyder S. and Nain A.K., Studies of molecular interaction in binary liquid mixtures by velocity and viscosity measurements, Acoustics Lett., 21, 21 (1998)
  10. Jacobson B., Intermolecular Free Lengths in Liquids in Relation to Compressibility, Surface Tension and Viscosity, Acta Chem. Scand, 1214 (1951)
  11. Palaniappan L. and Karthikeyan V., Study of Acoustical Parameters of Binary Liquid Mixtures at 298K, Indian J Phys.,79(2), 155 (2005)
  12. Nithiyanantham S. and Palaniappan L., Ultrasonic Study of the Self-Association of Aniline in Ethanol-Cyclohexane Mixtures, Acta Ciencia Indica, 36(4), 533-538 (2005)
  13. Nithiyanantham S. and Palaniappan L., Correlation of the rates of solvolysis of tert-butyl chlorothioformate and observations concerning the reaction mechanism, Acta Ciencia Indica, 37(3), 382-392 (2006)
  14. Nithya R., Mullainathan S., Nithiyanantham S. and Rajasekaran R., Synthesis of some new pyrazolylfuropyrimidinethiones and triazolofuropyrimidinethiones, E Journal of Chemistry, 6(1), 138(2009)
  15. Nithiyanantham S. and Palaniappan L., Metals Materials and Processes, 20(3), 203 (2008)
  16. M. Satya Narayanamurthy, Curr Sci., 33, 364 (1964)
  17. Soitkar V.S. and Jajoo S.N., Acoust Lett.,7(12), 1984 (1991)
  18. Suryanarayana C.V., J Acoust Soc India, 13, 9 (1983)
  19. Fletcher A., Effect of carbon tetrachloride upon the self-association of 1-octanol, J Phys Chem.,73, 2217 (1969)
  20. Pimental G.C. and Maclellan A.L., The Hydrogen bond, (WH Freeman and Co, San Fransisco), (1960)
  21. B.Samuel Ebinezer, L.Palaniappan, Effect of Field Strength in the Velocity Anisotropy of Ferrofluids, J Phy Sci., 18(1), 11-21(2007)
  22. Palaniappan L. and Velusamy V., Ultrasonic study of human cerebrospinal fluid, Indian J Pure Appl Phys., 42, 591-594, (2004)
  23. Velusamy V., Nithiyanantham S., Palaniappan L., Ultrasonic study of adsorption in disaccharide (maltose) metabolism, Main Group Chemistry, 6(1), 53-61, (2007)
  24. Jerie K., Baranowski A., Przybylski J. and Glinski J., Ultrasonic and positron annihilation studies of liquid solutions of i.91;垐 n/i.91;垐-hexanol in 1, 2-ethanediol,J Mol Liq., 111, 25-31, (2004)
  25. Saravanakumar K. and Kubendran T.R., Density and Viscosities for the Binary Mixtures of 1, 4-Dioxane and Benzene or Chlorobenzene at 303.15, 308.15, 313.15 K and a Pressure of 0.1MPa, Research Journal of Chemical Sciences, 2(4), 50-56(2012)