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Transition Metal Complexes of Bidentate Ligand N-aminoquinolino-2-one and Anthranilic Hydrazide

Author Affiliations

  • 1Department of chemistry, College of Science University of Mosul, IRAQ

Res.J.chem.sci., Volume 3, Issue (12), Pages 50-53, December,18 (2013)

Abstract

This research involves the preparation of some transition metal complexes of Ni(II), Cu(II), Zn(II) and Hg(II) with the ligand N-aminoquinolino-2-one(L) andmixed ligands such as anthranilic hydrazide as abidentate ligand. Complexes of the general formula [M(L1)Cl2], [M(L1)cl2] and[M(L1)2(L2)]Cl2 were prepared through direct reaction of the above ligand with the metal respectively (1:1), (1:2) and (1:2:1)ligand with anthranilic acid. These complexes characterized by means of Microanalysis (M) molar conductance measurements, Magnetic measurements, Infrared and electronic spectral techniques.

References

  1. Hyappa P.B.,Young j.k.,Moore J.S and Suslic Dendrimer-Metalloprophyrine:Synthesis and Catalysis, J. Am.Chem.Soc., 118,5708 (1996)
  2. Castillo-Blum S.E. and Barba-Behrens N., Coordination chemistry of some biologically active ligands, Coord.Chem.Rev., (3), 196 (2000)
  3. Mohan G.,and Rajesh N., Synthesis and anti- inflammatory activity of N-Pyridinobenzamid-2-carboxylic acid and its metal chelates, Indian J.Pharm, 24, 207 (1992)
  4. Kong D., Reibbenspies J., Mao J. and Clearfield A., Novel 30-membered octaazama-crocyclic ligand: synthesis, characterization thermodynamic stabilities and DNA cleavage activity of homodinuclear copper and nichel complexes, Inorg.Chim .Acta, 342,158 (2003)
  5. Lewis R.J., Smith T.S., Karzynski A., Max well A.J., Wonacott and Wingley D.B, The nature of inhibition of DNA gyrase by the Coumarins and the cyclothialidines revealed by X-ray crystallography, EMBOJ., 15, 1412-1420 (1996)
  6. Tai-Chi W., Kuan – Han L., Yeh – long C., Shorong – Shii L and T. Cherng – Chyi T., Synthesis and anticancer evaluation of certain Y-aryloxymethyl -a- methylene –Y– phenyl –Y– butyrolactones, Bioorg. Med. Chem., 19, 2773–2776 (1998)
  7. Ghulam Q., Nasim H.R., Zhi-Jin F., Bin Land Xiufeng L., synthesis, herbicidal, fungicidal and insecticidal evaluation of 3-(dichlophenyl) -iso coumarins dichlorophenyl)-3,4- dihydrois coumarins, J.Braz. chem. Soc., 18, 6 (2007)
  8. Manfredin S., Danicle S., Roberto F., Rita B, Silvia V,.Sigrid H., Jan B and Erik D., Retinoic Acid Conjugates as potenial Antiumor Agents: Synthesis and Biological Activity of Conjuates with Ara-A, Ara-C, 3(2H)- furanone, and Aniline Mustard Moieties, J.Med.Chem., 40(23), 3851-3857 (1997)
  9. Borges F., Roleira F., Milhazes N., Santana L and Uriarte E., Simple coumarine and analoges in Medicinal chemistry chem., 12, 88-916 (2005)
  10. Kennedy O., Thornes R.D., Coumarins: Biology, Applications and Mode of Action. Wiley & Sons, Chichester, (1997)
  11. AL-Amiery A.H, AL-Bayati I.H,Radi F.,Synthesis, pectroscopic and antimicrobial studies of transition metal complexes of N-amino quinolone derivatives, British. J.Pharm. Toxi, 2, 5-11 (2011)
  12. AL-Omar A.,EL-Azab A.S., EL-Obeid W.A and Abdel W.,Synthesis of some new 4(3H)-quinazolinone analogues, J.sandi chem. Soc.,10, 113 (2006)
  13. AL-Bayati R.F.,Radi M.F., Synthesis of novel 2-quinolone elerivative. A.J. pure chem.,4(10), 228-232 (2010)
  14. Vogel A.I., A text Book of Quantitative Inorganic Analysis Including Elementary Instrumental Analysis, 3461 (1967)
  15. Geary W.j.,The use of conductivity measurement in organic solvent for characterization of coordination compounds, Coord.Chem.Rev., , 8 (1971)
  16. Ali I.H., preparation and investigation of some complexes of Cobalt(II), Nickel(II), copper(I), (II), with Schiff Bases Derivation Acid Hydrazide, MSC. Thesis, college of Education , University of Mosul (1999)
  17. Cotton F.A. and Wilkinsan D., Advensed Inorganic Chemistry 5th ed Wiley-Inter Science,New York (1988)
  18. Chaudhary R. and Shelly, Synthesis, Spectral and Pharmacological Study of Cu(II), Ni(II), and Co(II) Coordination Complexes, Res.J.Chem.Sci.,1(5), 1-5 (2011)
  19. Ali I.H., Synthesis and characterization of some complexes Mn(II),Fe(II),Co(II),Ni(II),Cu(II), and Zn(II) with Schiff bases derived from anthranilic hydrazide with salicyldehyde and benzyldehyde, Tik. J.Pur.sci., 14(1), (2009)
  20. Hussein S.S.,Mostaafa M.,Stefen S.L. and Abdel-Aziz E.,Structural Diversity of 3d Complexes of an Isatinic Quinolyl Hydrazone , Res. J.Chem.Sci., 1(5),67-72(2011)
  21. Kulkarni P.A., Habib I.S., Saraf V.D. and Deshpande M.M., Synthesis, spectral analysis and antimicrobial activity of some new transition metal complexes derived from 2, 4-dihydroxy acetophenone, Res.J.Chem.Sci., 3, 107 (2012)
  22. Mostafa M., Metal Chelates of Hydrazone Ligand Chelating Tendencies of 2-Carboxy –Phenyihydrazoacetoacetanilide (2-Cphaa) Ligand, Res.J.Chem.Sci.,1(7), 1-4 (2011)
  23. Buttrus N.H and Tariq F.S.,Synthesis and structural studies on some transition metal complexes of bis –(benzimidazole-2-thio) ethane, propane and butane ligands, Res.J.Chem.Sci.,2(6), 43-49 (2012)