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Synthesis, Characterization and Catalytic Properties of Nickel Substituted Copper Ferrospinel Nanoparticles

Author Affiliations

  • 1 Department of Chemistry, the Institute of Science, 15, Madam Cama Road, Mumbai, INDIA

Res. J. Material Sci., Volume 1, Issue (5), Pages 1-9, June,16 (2013)

Abstract

The nickel substituted copper ferrite nanoparticles (NixCu1-xFe2O4), where x = 0.0, 0.2, 0.4, 0.6, 0.8, 1.0) were prepared by simple and economic coprecipitation method and characterized by various physicochemical methods such as XRD analysis, IR spectrometry, FEG-SEM and EDS. The XRD analysis showed that all the samples formed have single-phase cubic structure. The FEG-SEM analysis data reveals that the particle size of the compounds lie in the range 13.9 to 31.8nm. The nanoparticles synthesized are useful in the catalytic reactions and are ~100% selective for the acetylation of selected phenols. The catalysts were found to be magnetically separable and reusable without any further treatment. These ferrospinel nanoparticles were found to have better catalytic activity as compared to the corresponding metal oxides. The present nanoparticle catalysts offer high yields in a short reaction time and moderate reaction conditions.

References

  1. Xu Q., Wei Y., Liu Y., Ji X., Yang L. and Gu M., Solid State Sci., 11(2), 4/2-4/8 (2009)
  2. Iian M.B., Magnetic Material Beijng, I Singhua University Press, (2001)
  3. Blasse G., Philips Res. Rep. Suppl., 3, 96 (1964)
  4. O'Keefe M., J. Phys. Chem. Solids, (1961)
  5. Ghorpade S.P., Darshane V.S. and Dixit S.G., Appl. Catal. A: Gen., 166, 135 (1998)
  6. Narsimhan C.S. and Swamy C.S., Appl. Catal., 2, 315 (1982)
  7. Sloczynski J., Janas J., Machej I., Rynkowski J. and Stoch J., Appl. Catal B, 24(1), 45 (2000)
  8. Lee H., Jung J., Kim H., Chung Y., Kim T.J., Lee S.J., Oh S., Kim Y.S., Song L.K., Catal. Lett., 122, 281 (2008)
  9. Wang X., Yang G., Zhang Z., Yan L. and Meng J., Dyes Pigm., 74 (2), 269 (2007)
  10. Ajayan P.M., Redlich P. and Ru”hle M., J. Micro, 185 (2), 2/5-282 (1997)
  11. Hu J., Li L-s, Yang W., Manna L. and Wang L-w, Alvisatos A.P., Science, 292 (5524) , 2060 (2001)
  12. Pena M.A. and Pierro J.L.G., Chem. Rev., 101(7), 1981 (2001)
  13. Baykal A., Kasapoglun, Durmus Z., Kalvas H., Ioprak M.S. and Koseogla Y., Iurk J. chem., 33, 33 (2009)
  14. Gunjakar J.L., More A.M., Gurav K.V. and Lokhande C.D., Appl. Surf. Sci., 254(18), 5844 (2008)
  15. Vedejs E., Bennets N.S., Conn L.M., Diver S.T., Gingras M., Lin S., Oliver P.A. and Peterson M. J., J. Org. Chem., 58, 7286 (1993)
  16. Sano T., Ohashi K. and Oriyama T., Synthesis, 1141 (1999)
  17. D'Sa B.A. and Verkade J.G., J. Org. Chem., 61, 5702 (1996)
  18. Vedejs E. and Daugulis O., J. Org. Chem., 61, 2963 (1996)
  19. Olah G.A., Friedel-Craft’s and Related Reactions, Vol. III, Interscience Publishers, New York, 1606 (1964)
  20. Lee S. and Park J.H., J. Mol. Catal. A: Chem., 194, 49 (2003)
  21. Spagnol M., Gilbert L., Alby D., Desmurs J.R. and Rattoy S. (Eds.), The Roots of Organic Development, Elsevier, Amsterdam, 29 (1996)
  22. Li C., Liu W. and Zhao Z., Catal. Commun., 8, 1834 (2007)
  23. Tamaddon F., Ali Amrollahi M. and Sharafat L., Tetrahedron Lett., 46, 7481 (2005)
  24. Ghosh R.B., Maiti S. and Chakraborty A., Tetrahedron Lett., 46, 147 (2005)
  25. Zhdanov R.I. and Zhenadavora S.R., Synthesis, 222 (1975)
  26. Green T.W. and Wutz P.G.M., Protective Groups in Organic Synthesis, second edn., Wiley, New York, (1991)
  27. Bauer K., Garbe D. and Sturburg H., Commmon Fragrance and Flavor Materials: Preparation and Uses, fourth edn., Wiley – VCH, (2001)
  28. Choudhary B.M., Lakshmi Kantam M., Neerja V. and Bandyophadhyay T., Reddy P.N., J. Mol. Catal. A: Chem., 140, 25 (1999)
  29. Dube G.R. and Darshane V.S., Bull. Chem. Soc. Jpn., 64, 2449 (1991)
  30. Yur’eva T.M., Boreskov G.K., Zharkov V.I., Karakchivev L.G., Popovski V.V. and Chigrina V.A., Kinet. Katal., 9 1063 (1968)
  31. Poole Charles P. and Owens F.J. Jr., Introduction to Nanotechnology, John Wiley and Sons, (2003)