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Kinetics Study of Catio-radically Polymerization of Aniline Catalyzed by Maghnite-Na Clay Catalyst Layered (Western Algeria)

Author Affiliations

  • 1Université d’Oran Es-senia, Département de chimie, Faculté des sciences, BP 1524.El M’nouar 31000 Oran ALEGERIA

Res. J. Material Sci., Volume 1, Issue (4), Pages 1-8, May,16 (2013)

Abstract

The polymerization of aniline with oxidant (Kcatalyzed by Maghnite-H in chloroform (CDCl) as solvant at 0°C was investigated. The effects of the amounts of Mag-H, agent oxidant, water and temperature on the polymerization of aniline were studied. The polymerization yield increased as the proportions of catalyst and oxidant were increased in temperature range T = 0°C at T = 5°C. The reactions were monitored by gel permeation chromatography, H-NMR spectroscopy and FTIR spectroscopy.

References

  1. Kim B.H., Jung J.H., Kim J.W., Choi H.J. and Joo j, Synth Met, 117, 115 (2001)
  2. Arsalani N and Hayatifar N., Polym Int , 54, 933 (2005 )
  3. Asturias G.E., MacDiarmid A.G., McCall R.P. and Epstein A.J., Synth. Met, 29, E157 (1989)
  4. Chuang T.H., Guo W., Cheng K.C., Chen SW., Wang H.T. and Yen Y.Y., J Polym Res, 11, 169 (2004)
  5. Kannan C., Devi M.R., Muthuraja K., Esaivani K. and Sudalai Vadivoo V. Green catalytic Polymerization of Styrene in the Vapor phase over Alumina, Res.J.chem.sci.,2(7), 27-35 (2012)
  6. Shukur Majid M., Kadhim. F. Al-Sultani and Hassan Mohammed N. Preparation of Alkali Lead Glass and Glass Ceramic Compositions as Electrical Insulators., Res.J.chem.sci.,2(2), 28-34 (2012)
  7. Sanchez C., Soler-Illia J.A., Ribot F., Lalot T., Mayer C.R. and Cabuil V., Designed hybrid Organic-inorganic nanocomposites from functional nanobuilding blocks,Chem Mater, 13(10), 3061-3083(2001)
  8. Belbachir M. and Bensaoula A, U.S. Pat. 6, 274, 527B (2001)
  9. Harrane A., Meghabar R and Belbachir M, Int J Mol Sci ;3, 790 (2002)
  10. Joel O.F., Durueke U.J., Kinigoma B.S. and Nwokoye C.U., Evaluation of Effect of Different Concentrations of Shale on Rheological Properties of Water-Based Mud , Res. J. Chem. Sci.,2(10), 13-19 (2012)
  11. Epstein J., McCall R.P., Ginder J.M and MacDiarmid A.G., in: R.J.H.Clark (Ed.), Spectro. of adv. Materials, Wiley, Chichester,UK, 305–319(1991)
  12. Yildirim K., Altun S. and Ulcay Y. DSC Analysis of Partially Oriented (Poy) and Textured Poly (Ethylene Terephthalate) Yarns, Res.J.chem.sci.,1(9), 57-66(2011)
  13. Bçak N., Filiz S and enkal E.S., Synthetic Metals, 155,105–109 (2005)
  14. Yahiaoui A and Belbachir M., Ring-opening Polymerization of Styrene oxide with Mag-H as eco-catalyst, Journal of Applied Polymer Science, 100, 1681–1687(2006)
  15. Yahiaoui A., et al., An acid exchanged montmorillonite clay-catalyzed synthesis of poly- Epichlorhydrin; Int. J. Mol.Sci., 4, 548-561 (2003)
  16. Bangale Sachin and Bamane Sambaji. Synthesis, Characterization and Hydrophilic Properties of Nanocrystalline ZnFe2O4 Oxide, Res. J. Recent Sci.,1(ISC-2011) , 202-206 (2012)
  17. Rasika D., Wang X., Gamini R.M., Elsenbauer R.L., Chem Commun., 976 ( 2006)
  18. Cao Y., Smith P. and Heeger A.J., Spectroscopic studies of polyaniline in solution and in spin-cast films, Synth. Met., 32, 263 (1989)
  19. Shinde Santosh S. and Jachak Madhukar N.Synthesis and fluorescent behavior of Pyran and Pyridine-3, 5-dicarbonitrile derivatives, Res. J. Recent Sci., 1(ISC-2011), 67-72 (2012)