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Effect of Various Factors on the Adsorption of Methylene Blue on Silt Fractionated from Bijoypur Soil, Bangladesh

Author Affiliations

  • 1 Department of Chemistry, University of Dhaka, Dhaka-1000, BANGLADESH

Int. Res. J. Environment Sci., Volume 2, Issue (6), Pages 1-7, May,22 (2013)


Silt obtained from the fractionation of Bijoypur (Netrokona, Bangladesh) soil having the particle size (53 – 140 µm) was used as an adsorbent for the removal of Methylene Blue (MB) from aqueous solution. The effect of various factors (pH, temperature and adsorbent dose) on adsorption of MB on silt fraction was investigated. The effect of pH shows that the amount adsorbed increased with the increase of pH of solution. The equilibrium adsorption isotherms were analyzed by Langmuir and Freundlich equations. Both Langmuir and Freundlich models can describe theadsorption equilibrium but the Langmuir model shows better agreement. Theamount adsorbed increased with the increase of temperature suggests the formation of dimer in the contact region. SEM micrographs and differential molar isosteric heat of adsorption (H) calculated at different surface coverage, indicate that the surface is heterogeneous having energetically different adsorption sites. Values of n calculated from Freundlich plots indicate that adsorption of MB on silt is spontaneous. At high surface coverage, the differential heat of adsorption versus surface coverage plot shows maximum value indicating the occurrence of structural rearrangement in the adsorbate. With the increase of adsorbent dose, amount adsorbed increased due to the increased surface area of adsorbent.


  1. Pare S., Persson I., Guel B. and Daniel, L., Trivalentchromium removal from aqueous solution using raw naturalmixed clay from BURKINA FASO, Int. Res. J.Environment Sci., 2(2), 30-37 (2013)
  2. Al-Sultani K.F. and Al-Seroury F.A., Characterization theremoval of phenol from aqueous solution in fluidized bedcolumn by rice husk adsorbent, Res. J. Recent. Sci., 1(ISC-2011) , 145-151 (2012)
  3. Macedo J.D.S., Da Costa Júnior N.B., Almeida L.E., DaSilva Vieira E.F., Cestari A.R., Gimenez I.de F., CarreńoN.L.V. and Barreto L.S., Kinetic and calorimetric study ofthe adsorption of dyes on mesoporous activated carbonprepared from coconut coir dust, J. Colloid Interface Sci.,298, 515–522 (2006)
  4. Mane R.S. and Bhusari V.N., Removal of color (dyes) fromtextile effluent by adsorption using orange and banana peel,Intl. J. Engg. Res. Applic (IJERA), 2(3), 1997-2004 (2012)
  5. Yousefi N., Fatehizadeh A., Azizi E., Ahmadian M.,Ahmadi A.K., Rajabizadeh A. and Toolabi A., Adsorptionof reactive black 5 dye onto modified wheat straw: isothermand kinetics study, Sacha J. Environ. Stud., 1(2), 81-91(2011)
  6. Filhoa N.C., Venancioa E.C., Barriquelloa M.F.,Hechenleitnerb A.A.W. and Pinedab E.A.G., Methyleneblue adsorption onto modified lignin from sugar canebagasse, Ecl. Quim. Sao Paulo., 32(4), 63-70 (2007)
  7. Horsfall Jnr M. and Spiff A.I., Effects of temperature on thesorption of Pb2+ and Cd2+ from aqueous solution bycaladium bicolor (wild cocoyam) biomass, Elec. J.Biotech., 8(2), 162-169 (2005)
  8. Bassim M. and Al-Karagoli H., Removal of MG from waterby using residual tea leaves as adsorbent, Natural J. Chem.,36, 690-699 (2009)
  9. Elass K., Laachach A., Laoui A. and Azzi M., Removal ofmethylene blue from aqueous solution using ghassoul, alow-cost adsorbent, Appl. Eco. Environ. Res., 8(2), 153-163(2010)
  10. Alau K.K., Gimba C.E. and Kagbu J.A., Removal of dyesfrom aqueous solution using neem (Azadirachta Indica)husk as activated carbon, Arch. Appl. Sci. Res., 2(5), 456-461 (2010)
  11. Namasivayam C. and Yamuna R.T., Utilizing biogas residual slurry for dye adsorption, American DyestuffReporter, (August 1994)
  12. Rubin E., Rodriguez P., Herrero R., Cremades J., Barbara I.and Vicente M.E.S., Removal of methylene blue fromaqueous solutions using as biosorbent sargassum muticum,J. Chem. Technol. Biotechnol., 80, 295-298 (2005)
  13. Markovska L., Meshko V. and Noveski V., Adsorption ofbasic dyes in a fixed bed column, Korean J. Chem Engg.,14(2), 190-195 (2001)
  14. Khandelwal D.H. and Ameta R., Use of photo-fentonreagent in the degradation of basic yellow 2 in aqueousmedium, Res. J. Recent Sci., 2(1), 39-43 (2013)
  15. Singh A.K., Prakash D. and Shahi S.K., Decolorization ofthe textile dye (Brown GR) by isolated Aspergillus strainfrom meerut region, Int. Res. J. Environment Sci., 2(2), 25-29 (2013)
  16. Kumar U. and Acharya J., Fixed bed column study for theremoval of lead from aquatic environment by NCRH, Res.J. Recent Sci., 2(1), 9-12 (2013)
  17. Iqbal M.J. and Ashiq M.N., Thermodynamics of adsorptionof dyes from aqueous media on activated charcoal, J. Res.Sci., 18(2), 91-99 (2007)
  18. Alessandro Delle Site, Factors affecting sorption of organiccompounds in natural sorbent-water systems and sorptioncoefficients for selected pollutants, J. Phys. Chem. Ref.Data., 30(1), 187-253 (2001)
  19. Hema M. and Arivoli S., Comparative study on theadsorption kinetics and thermodynamics of dyes onto acidactivated low cost carbon, Intl. J. Phys. Sci., 2(1), 10-17(2007)
  20. Parfiit G.D. and Ochester C.H., Adsorption from solution atthe solid/liquid interface, Academic press, London. 9-12,223-331 (1983)
  21. Zaker Y., Investigation of bijoypur clay fractions as lowcost adsorbents, M.S. Thesis, Department of Chemistry,University of Dhaka, Dhaka, Bangladesh, (2010)
  22. Shawabkeh R.A. and Tutunji M.F., Experimental study and modeling of basic dye sorption by diatomaceous clay,Appl. Clay Sci., 24, 111 – 120 (2003)
  23. Day P.R., Particle formation and particle size analysis,international methods of soil analysis, (eds. CA Black, DDEvans, JL White, LE Ensminger and FE Clark). AgronomyMonograph, Part-I, 545-567 (1965)
  24. Zaker Y., Hossain M.A., Islam M.S. and Islam T.S.A.,Physico-chemical characterization of silt fractionated frombijoypur soil, J. Asiat. Soc. Bangladesh, in press (2013)
  25. Gurses A., Dogar C., Yalcin M., Acikyildiz M., Bayrak R.and Karaca S., The adsorption kinetics of the cationic dye,MB onto clay, J. Hazard. Mat., B131, 217-228 (2006)
  26. Suteu D. and Bilba D., Equilibrium and kinetic study ofreactive dye brilliant red HE-3B adsorption by activatedcharcoal, Acta. Chim. Slov., 52, 73-79 (2005)
  27. Marcelo J.A., Laura E.V., Valera P. and Carlos P.de P.,Methylene blue dimerization does not interfare in surface area measurement of kaolinite and soil, Clay and ClayMinerals, 49(2), 168-173 (2001)
  28. Fomkin A.A., Adsorption of gases, vapors and liquids by microporous adsorbents, Adsorption, 11, 425-436 (2005)
  29. Bangham D.H., The gibbs adsorption equation and adsorption on solids, Trans Faraday Soc., 33, 805-809(1937)
  30. Bering B.P., Myers A. and Serpinsky V.V., Problem iinertnosti adsorbentov, Doklady Akademii Nauk SSSR, 193,119-122 (1970)